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Diffstat (limited to 'inst/doc')
| -rw-r--r-- | inst/doc/Rplots.pdf | 23902 | ||||
| -rw-r--r-- | inst/doc/mkin.Rnw | 25 | ||||
| -rw-r--r-- | inst/doc/mkin.pdf | bin | 176018 -> 178902 bytes | |||
| -rw-r--r-- | inst/doc/references.bib | 7 |
4 files changed, 23929 insertions, 5 deletions
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%%\VignetteIndexEntry{Routines for fitting kinetic models with one or more state variables to chemical degradation data}
%%VignetteDepends{FME}
%%\usepackage{Sweave}
@@ -78,7 +79,7 @@ barrier for \RR{} newcomers. \subsection{Data format}
The following listing shows example dataset C from the FOCUS kinetics
-report as distributed with the \Rpackage{kinfit} package
+report as distributed with the \Rpackage{mkin} package
<<FOCUS_2006_C_data, echo=TRUE, eval=TRUE>>=
library("mkin")
@@ -101,8 +102,9 @@ as shown in the following listing <<data_format, echo=TRUE>>=
example_data <- data.frame(
+ name = rep("parent", 9),
time = c(0, 1, 3, 7, 14, 28, 63, 91, 119),
- parent = c(85.1, 57.9, 29.9, 14.6, 9.7, 6.6, 4, 3.9, 0.6)
+ value = c(85.1, 57.9, 29.9, 14.6, 9.7, 6.6, 4, 3.9, 0.6)
)
@
@@ -122,12 +124,23 @@ SFORB_SFO <- mkinmod( m1 = list(type = "SFO"))
@
+The model definitions given above define sets of linear first-order ordinary
+differential equations. In these cases, a coefficient matrix is also returned.
+
+Other models that include time on the right-hand side of the differential
+equation are the first-order multi-compartment (FOMC) model and the
+Hockey-Stick (HS) model. At present, only the FOMC model can only be used, and
+only for the parent compound.
+
\subsection{Fitting the model}
Then the model parameters should be fitted to the data. The function
\Robject{mkinfit} internally creates a cost function using \Robject{modCost}
from the \Rpackage{FME} package and the produces a fit using \Robject{modFit}
-from the same package.
+from the same package. In cases of linear first-order differential
+equations, the solution used for calculating the cost function is based
+on the fundamental system of the coefficient matrix, as proposed by
+\citet{bates88}.
<<model_fitting, echo=TRUE>>=
# Do not show significance stars as they interfere with vignette generation
@@ -136,8 +149,10 @@ SFO.fit <- mkinfit(SFO, FOCUS_2006_C) summary(SFO.fit)
SFORB.fit <- mkinfit(SFORB, FOCUS_2006_C)
summary(SFORB.fit)
-SFO_SFO.fit <- mkinfit(SFO_SFO, FOCUS_2006_D)
-summary(SFO_SFO.fit)
+SFO_SFO.fit <- mkinfit(SFO_SFO, FOCUS_2006_D, plot=TRUE)
+summary(SFO_SFO.fit, data=FALSE)
+SFORB_SFO.fit <- mkinfit(SFORB_SFO, FOCUS_2006_D, plot=TRUE)
+summary(SFORB_SFO.fit, data=FALSE)
@
\bibliographystyle{plainnat}
diff --git a/inst/doc/mkin.pdf b/inst/doc/mkin.pdf Binary files differindex 4d2e1d1..f963d1e 100644 --- a/inst/doc/mkin.pdf +++ b/inst/doc/mkin.pdf diff --git a/inst/doc/references.bib b/inst/doc/references.bib index b158eeb..24672e2 100644 --- a/inst/doc/references.bib +++ b/inst/doc/references.bib @@ -53,3 +53,10 @@ address = {Piacenza},
pages = {916--923}
}
+
+@Book{ bates88,
+ title = {Nonlinear regression and its applications},
+ author = {D. Bates and D. Watts},
+ year = {1988},
+ publisher = {Wiley-Interscience}
+}
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