From 1718d434efae26de02754c6622c43f4dc9e624b9 Mon Sep 17 00:00:00 2001 From: jranke Date: Thu, 15 Mar 2012 15:54:14 +0000 Subject: Update kinfit and mkin to the latest version published on BerliOS. git-svn-id: svn+ssh://svn.r-forge.r-project.org/svnroot/kinfit/pkg/mkin@17 edb9625f-4e0d-4859-8d74-9fd3b1da38cb --- DESCRIPTION | 25 +- R/DFOP.solution.R | 5 + R/FOMC.solution.R | 4 + R/HS.solution.R | 6 + R/SFO.solution.R | 4 + R/SFORB.solution.R | 9 + R/mkin_long_to_wide.R | 23 +- R/mkin_wide_to_long.R | 20 + R/mkinerrmin.R | 20 + R/mkinfit.R | 398 +- R/mkinmod.R | 154 +- R/mkinplot.R | 83 +- R/mkinresplot.R | 54 + R/mkinstart.R | 23 + inst/GUI/.RData | Bin 0 -> 17960 bytes inst/GUI/.Rhistory | 3 + inst/GUI/gdf-test.R | 12 + inst/GUI/simple-Gtk.R | 33 + inst/GUI/simple.R | 68 + inst/GUI/test.R | 17 + inst/doc/Rplots.pdf | 23902 +++++++++++++++++++++++++++++++++++++++ inst/doc/mkin.Rnw | 25 +- inst/doc/mkin.pdf | Bin 176018 -> 178902 bytes inst/doc/references.bib | 7 + inst/unitTests/runit.mkinfit.R | 28 +- inst/unitTests/runit.mkinmod.R | 61 +- man/DFOP.solution.Rd | 36 + man/FOCUS_2006_datasets.Rd | 2 +- man/FOMC.solution.Rd | 49 + man/HS.solution.Rd | 34 + man/SFO.solution.Rd | 29 + man/SFORB.solution.Rd | 36 + man/mkin_long_to_wide.Rd | 7 +- man/mkinerrmin.Rd | 1 - man/mkinfit.Rd | 31 +- man/mkinmod.Rd | 18 +- man/mkinplot.Rd | 6 +- man/mkinresplot.Rd | 64 + man/mkinstart.Rd | 38 + man/summary.mkinfit.Rd | 16 +- tests/doRUnit.R | 17 +- 41 files changed, 25196 insertions(+), 172 deletions(-) create mode 100644 R/DFOP.solution.R create mode 100644 R/FOMC.solution.R create mode 100644 R/HS.solution.R create mode 100644 R/SFO.solution.R create mode 100644 R/SFORB.solution.R create mode 100644 R/mkinresplot.R create mode 100644 R/mkinstart.R create mode 100644 inst/GUI/.RData create mode 100644 inst/GUI/.Rhistory create mode 100644 inst/GUI/gdf-test.R create mode 100644 inst/GUI/simple-Gtk.R create mode 100644 inst/GUI/simple.R create mode 100644 inst/GUI/test.R create mode 100644 inst/doc/Rplots.pdf create mode 100644 man/DFOP.solution.Rd create mode 100644 man/FOMC.solution.Rd create mode 100644 man/HS.solution.Rd create mode 100644 man/SFO.solution.Rd create mode 100644 man/SFORB.solution.Rd create mode 100644 man/mkinresplot.Rd create mode 100644 man/mkinstart.Rd diff --git a/DESCRIPTION b/DESCRIPTION index 7eabdf2..a2c760c 100644 --- a/DESCRIPTION +++ b/DESCRIPTION @@ -2,18 +2,19 @@ Package: mkin Type: Package Title: Routines for fitting kinetic models with one or more state variables to chemical degradation data -Version: 0.7-6 -Date: 2010-06-09 -Author: Johannes Ranke -Maintainer: Johannes Ranke -Description: Calculation routines based on the FOCUS Kinetics Report (2006). Includes - a function for conveniently defining differential equation models, choice of - the optimisation methods made available by the FME package (default is a - Levenberg-Marquardt variant). -Depends: FME +Version: 0.8-11 +Date: 2011-05-19 +Author: Johannes Ranke, Katrin Lindenberger +Maintainer: Johannes Ranke +Description: Calculation routines based on the FOCUS Kinetics Report (2006). + Includes a function for conveniently defining differential equation models, + model solution based on eigenvalues if possible or using numerical solvers + and a choice of the optimisation methods made available by the FME package + (default is a Levenberg-Marquardt variant). Please note that no warranty is + implied for correctness of results or fitness for a particular purpose. +Depends: FME, deSolve, kinfit +Suggests: RUnit License: GPL LazyLoad: yes LazyData: yes -Packaged: 2010-05-18 12:52:36 UTC; ranke -Repository: CRAN -Date/Publication: 2010-05-18 13:18:05 +URL: http://cran.r-project.org, http://developer.berlios.de/projects/mkin/ diff --git a/R/DFOP.solution.R b/R/DFOP.solution.R new file mode 100644 index 0000000..8531cfe --- /dev/null +++ b/R/DFOP.solution.R @@ -0,0 +1,5 @@ +DFOP.solution <- function(t, parent.0, k1, k2, g) +{ + parent = g * parent.0 * exp(-k1 * t) + + (1 - g) * parent.0 * exp(-k2 * t) +} diff --git a/R/FOMC.solution.R b/R/FOMC.solution.R new file mode 100644 index 0000000..8bd13d6 --- /dev/null +++ b/R/FOMC.solution.R @@ -0,0 +1,4 @@ +FOMC.solution <- function(t, parent.0, alpha, beta) +{ + parent = parent.0 / (t/beta + 1)^alpha +} diff --git a/R/HS.solution.R b/R/HS.solution.R new file mode 100644 index 0000000..4651a6a --- /dev/null +++ b/R/HS.solution.R @@ -0,0 +1,6 @@ +HS.solution <- function(t, parent.0, k1, k2, tb) +{ + parent = ifelse(t <= tb, + parent.0 * exp(-k1 * t), + parent.0 * exp(-k1 * tb) * exp(-k2 * (t - tb))) +} diff --git a/R/SFO.solution.R b/R/SFO.solution.R new file mode 100644 index 0000000..3a376e4 --- /dev/null +++ b/R/SFO.solution.R @@ -0,0 +1,4 @@ +SFO.solution <- function(t, parent.0, k) +{ + parent = parent.0 * exp(-k * t) +} diff --git a/R/SFORB.solution.R b/R/SFORB.solution.R new file mode 100644 index 0000000..45a4533 --- /dev/null +++ b/R/SFORB.solution.R @@ -0,0 +1,9 @@ +SFORB.solution = function(t, parent.0, k_12, k_21, k_1output) { + sqrt_exp = sqrt(1/4 * (k_12 + k_21 + k_1output)^2 + k_12 * k_21 - (k_12 + k_1output) * k_21) + b1 = 0.5 * (k_12 + k_21 + k_1output) + sqrt_exp + b2 = 0.5 * (k_12 + k_21 + k_1output) - sqrt_exp + + parent = parent.0 * + (((k_12 + k_21 - b1)/(b2 - b1)) * exp(-b1 * t) + + ((k_12 + k_21 - b2)/(b1 - b2)) * exp(-b2 * t)) +} diff --git a/R/mkin_long_to_wide.R b/R/mkin_long_to_wide.R index 45ee0a1..ca09b49 100644 --- a/R/mkin_long_to_wide.R +++ b/R/mkin_long_to_wide.R @@ -1,7 +1,28 @@ -mkin_long_to_wide <- function(long_data, time = "time") +# $Id: mkin_long_to_wide.R 96 2011-04-29 11:10:40Z jranke $ + +# Copyright (C) 2010-2011 Johannes Ranke +# Contact: mkin-devel@lists.berlios.de + +# This file is part of the R package mkin + +# mkin is free software: you can redistribute it and/or modify it under the +# terms of the GNU General Public License as published by the Free Software +# Foundation, either version 3 of the License, or (at your option) any later +# version. + +# This program is distributed in the hope that it will be useful, but WITHOUT +# ANY WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS +# FOR A PARTICULAR PURPOSE. See the GNU General Public License for more +# details. + +# You should have received a copy of the GNU General Public License along with +# this program. If not, see + +mkin_long_to_wide <- function(long_data, time = "time", outtime = "time") { colnames <- unique(long_data$name) wide_data <- data.frame(time = subset(long_data, name == colnames[1], time)) + names(wide_data) <- outtime for (var in colnames) { wide_data[var] <- subset(long_data, name == var, value) } diff --git a/R/mkin_wide_to_long.R b/R/mkin_wide_to_long.R index 21ab77b..995a9be 100644 --- a/R/mkin_wide_to_long.R +++ b/R/mkin_wide_to_long.R @@ -1,3 +1,23 @@ +# $Id: mkin_wide_to_long.R 59 2010-07-28 12:29:15Z jranke $ + +# Copyright (C) 2010 Johannes Ranke +# Contact: mkin-devel@lists.berlios.de + +# This file is part of the R package mkin + +# mkin is free software: you can redistribute it and/or modify it under the +# terms of the GNU General Public License as published by the Free Software +# Foundation, either version 3 of the License, or (at your option) any later +# version. + +# This program is distributed in the hope that it will be useful, but WITHOUT +# ANY WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS +# FOR A PARTICULAR PURPOSE. See the GNU General Public License for more +# details. + +# You should have received a copy of the GNU General Public License along with +# this program. If not, see + mkin_wide_to_long <- function(wide_data, time = "t") { colnames <- names(wide_data) diff --git a/R/mkinerrmin.R b/R/mkinerrmin.R index 7a922eb..ebed191 100644 --- a/R/mkinerrmin.R +++ b/R/mkinerrmin.R @@ -1,3 +1,23 @@ +# $Id: mkinerrmin.R 59 2010-07-28 12:29:15Z jranke $ + +# Copyright (C) 2010 Johannes Ranke +# Contact: mkin-devel@lists.berlios.de + +# This file is part of the R package mkin + +# mkin is free software: you can redistribute it and/or modify it under the +# terms of the GNU General Public License as published by the Free Software +# Foundation, either version 3 of the License, or (at your option) any later +# version. + +# This program is distributed in the hope that it will be useful, but WITHOUT +# ANY WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS +# FOR A PARTICULAR PURPOSE. See the GNU General Public License for more +# details. + +# You should have received a copy of the GNU General Public License along with +# this program. If not, see + mkinerrmin <- function(errdata, n.parms, alpha = 0.05) { means.mean <- mean(errdata$value_mean, na.rm=TRUE) diff --git a/R/mkinfit.R b/R/mkinfit.R index f8285fc..b742742 100644 --- a/R/mkinfit.R +++ b/R/mkinfit.R @@ -1,11 +1,36 @@ +# $Id: mkinfit.R 120 2011-09-02 14:25:35Z jranke $ + +# Copyright (C) 2010-2011 Johannes Ranke +# Contact: mkin-devel@lists.berlios.de +# The summary function is an adapted and extended version of summary.modFit +# from the FME package, v 1.1 by Soetart and Petzoldt, which was in turn +# inspired by summary.nls.lm + +# This file is part of the R package mkin + +# mkin is free software: you can redistribute it and/or modify it under the +# terms of the GNU General Public License as published by the Free Software +# Foundation, either version 3 of the License, or (at your option) any later +# version. + +# This program is distributed in the hope that it will be useful, but WITHOUT +# ANY WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS +# FOR A PARTICULAR PURPOSE. See the GNU General Public License for more +# details. + +# You should have received a copy of the GNU General Public License along with +# this program. If not, see + mkinfit <- function(mkinmod, observed, parms.ini = rep(0.1, length(mkinmod$parms)), state.ini = c(100, rep(0, length(mkinmod$diffs) - 1)), lower = 0, upper = Inf, fixed_parms = NULL, fixed_initials = names(mkinmod$diffs)[-1], + eigen = FALSE, plot = FALSE, quiet = FALSE, err = NULL, weight = "none", scaleVar = FALSE, + atol = 1e-6, ...) { mod_vars <- names(mkinmod$diffs) @@ -16,18 +41,6 @@ mkinfit <- function(mkinmod, observed, # Name the parameters if they are not named yet if(is.null(names(parms.ini))) names(parms.ini) <- mkinmod$parms - # Create a function calculating the differentials specified by the model - mkindiff <- function(t, state, parms) { - time <- t - diffs <- vector() - for (box in mod_vars) - { - diffname <- paste("d", box, sep="_") - diffs[diffname] <- with(as.list(c(time,state, parms)), - eval(parse(text=mkinmod$diffs[[box]]))) - } - return(list(c(diffs))) - } # Name the inital parameter values if they are not named yet if(is.null(names(state.ini))) names(state.ini) <- mod_vars @@ -45,6 +58,40 @@ mkinfit <- function(mkinmod, observed, names(state.ini.optim) <- paste(names(state.ini.optim), "0", sep="_") } + # Set upper limit for formation fractions to one if formation fractions are + # directly defined and if no user input for upper limit is given + if (all(upper==Inf) & any(grepl("f_", names(parms.ini)))==TRUE){ + upper=c( rep(Inf,length(parms.optim))) + upper[grep("f_", names(parms.optim))]=1 + upper=c(rep(Inf, length(state.ini.optim)), upper) + } + + # Decide if the solution of the model can be based on a simple analytical + # formula, the spectral decomposition of the matrix (fundamental system) + # or a numeric ode solver from the deSolve package + if (length(mkinmod$map) == 1) { + solution = "analytical" + } else { + if (is.matrix(mkinmod$coefmat) & eigen) solution = "eigen" + else solution = "deSolve" + } + + # Create a function calculating the differentials specified by the model + # if necessary + if(solution == "deSolve") { + mkindiff <- function(t, state, parms) { + time <- t + diffs <- vector() + for (box in mod_vars) + { + diffname <- paste("d", box, sep="_") + diffs[diffname] <- with(as.list(c(time,state, parms)), + eval(parse(text=mkinmod$diffs[[box]]))) + } + return(list(c(diffs))) + } + } + cost.old <- 1e100 calls <- 0 out_predicted <- NA @@ -60,19 +107,67 @@ mkinfit <- function(mkinmod, observed, odeparms <- c(P[(length(state.ini.optim) + 1):length(P)], parms.fixed) outtimes = unique(observed$time) + evalparse <- function(string) + { + eval(parse(text=string), as.list(c(odeparms, odeini))) + } - # Solve the ode - out <- ode( - y = odeini, - times = outtimes, - func = mkindiff, - parms = odeparms) - + # Solve the system + if (solution == "analytical") { + parent.type = names(mkinmod$map[[1]])[1] + parent.name = names(mkinmod$diffs)[[1]] + o <- switch(parent.type, + SFO = SFO.solution(outtimes, + evalparse(parent.name), + evalparse(paste("k", parent.name, "sink", sep="_"))), + FOMC = FOMC.solution(outtimes, + evalparse(parent.name), + evalparse("alpha"), evalparse("beta")), + DFOP = DFOP.solution(outtimes, + evalparse(parent.name), + evalparse("k1"), evalparse("k2"), + evalparse("g")), + HS = HS.solution(outtimes, + evalparse(parent.name), + evalparse("k1"), evalparse("k2"), + evalparse("tb")), + SFORB = SFORB.solution(outtimes, + evalparse(parent.name), + evalparse(paste("k", parent.name, "bound", sep="_")), + evalparse(paste("k", sub("free", "bound", parent.name), "free", sep="_")), + evalparse(paste("k", parent.name, "sink", sep="_"))) + ) + out <- cbind(outtimes, o) + dimnames(out) <- list(outtimes, c("time", sub("_free", "", parent.name))) + } + if (solution == "eigen") { + coefmat.num <- matrix(sapply(as.vector(mkinmod$coefmat), evalparse), + nrow = length(mod_vars)) + e <- eigen(coefmat.num) + c <- solve(e$vectors, odeini) + f.out <- function(t) { + e$vectors %*% diag(exp(e$values * t), nrow=length(mod_vars)) %*% c + } + o <- matrix(mapply(f.out, outtimes), + nrow = length(mod_vars), ncol = length(outtimes)) + dimnames(o) <- list(mod_vars, outtimes) + out <- cbind(time = outtimes, t(o)) + } + if (solution == "deSolve") + { + out <- ode( + y = odeini, + times = outtimes, + func = mkindiff, + parms = odeparms, + atol = atol + ) + } # Output transformation for models with unobserved compartments like SFORB out_transformed <- data.frame(time = out[,"time"]) for (var in names(mkinmod$map)) { - if(length(mkinmod$map[[var]]) == 1) { + if((length(mkinmod$map[[var]]) == 1) || solution == "analytical") { out_transformed[var] <- out[, var] } else { out_transformed[var] <- rowSums(out[, mkinmod$map[[var]]]) @@ -90,19 +185,53 @@ mkinfit <- function(mkinmod, observed, # Plot the data and current model output if requested if(plot) { outtimes_plot = seq(min(observed$time), max(observed$time), length.out=100) - out_plot <- ode( - y = odeini, - times = outtimes_plot, - func = mkindiff, - parms = odeparms) + if (solution == "analytical") { + o_plot <- switch(parent.type, + SFO = SFO.solution(outtimes_plot, + evalparse(parent.name), + evalparse(paste("k", parent.name, "sink", sep="_"))), + FOMC = FOMC.solution(outtimes_plot, + evalparse(parent.name), + evalparse("alpha"), evalparse("beta")), + DFOP = DFOP.solution(outtimes_plot, + evalparse(parent.name), + evalparse("k1"), evalparse("k2"), + evalparse("g")), + HS = HS.solution(outtimes_plot, + evalparse(parent.name), + evalparse("k1"), evalparse("k2"), + evalparse("tb")), + SFORB = SFORB.solution(outtimes_plot, + evalparse(parent.name), + evalparse(paste("k", parent.name, "bound", sep="_")), + evalparse(paste("k", sub("free", "bound", parent.name), "free", sep="_")), + evalparse(paste("k", parent.name, "sink", sep="_"))) + ) + out_plot <- cbind(outtimes_plot, o_plot) + dimnames(out_plot) <- list(outtimes_plot, c("time", sub("_free", "", parent.name))) + } + if(solution == "eigen") { + o_plot <- matrix(mapply(f.out, outtimes_plot), + nrow = length(mod_vars), ncol = length(outtimes_plot)) + dimnames(o_plot) <- list(mod_vars, outtimes_plot) + out_plot <- cbind(time = outtimes_plot, t(o_plot)) + } + if (solution == "deSolve") { + out_plot <- ode( + y = odeini, + times = outtimes_plot, + func = mkindiff, + parms = odeparms) + } out_transformed_plot <- data.frame(time = out_plot[,"time"]) - for (var in names(mkinmod$map)) { - if(length(mkinmod$map[[var]]) == 1) { + for (var in obs_vars) { + if((length(mkinmod$map[[var]]) == 1) || solution == "analytical") { out_transformed_plot[var] <- out_plot[, var] } else { out_transformed_plot[var] <- rowSums(out_plot[, mkinmod$map[[var]]]) } } + out_transformed_plot <<- out_transformed_plot plot(0, type="n", xlim = range(observed$time), ylim = range(observed$value, na.rm=TRUE), @@ -124,8 +253,17 @@ mkinfit <- function(mkinmod, observed, } fit <- modFit(cost, c(state.ini.optim, parms.optim), lower = lower, upper = upper, ...) - # We need the function for plotting - fit$mkindiff <- mkindiff + # We need to return some more data for summary and plotting + fit$solution <- solution + if (solution == "eigen") { + fit$coefmat <- mkinmod$coefmat + } + if (solution == "deSolve") { + fit$mkindiff <- mkindiff + } + if (plot == TRUE) { + fit$out_transformed_plot = out_transformed_plot + } # We also need various other information for summary and plotting fit$map <- mkinmod$map @@ -161,54 +299,109 @@ mkinfit <- function(mkinmod, observed, n.optim <- n.k.optim + n.initials.optim if ("alpha" %in% names(parms.optim)) n.optim <- n.optim + 1 if ("beta" %in% names(parms.optim)) n.optim <- n.optim + 1 + if ("k1" %in% names(parms.optim)) n.optim <- n.optim + 1 + if ("k2" %in% names(parms.optim)) n.optim <- n.optim + 1 + if ("g" %in% names(parms.optim)) n.optim <- n.optim + 1 + if ("tb" %in% names(parms.optim)) n.optim <- n.optim + 1 errmin.tmp <- mkinerrmin(errdata.var, n.optim) errmin[obs_var, c("err.min", "n.optim", "df")] <- errmin.tmp } fit$errmin <- errmin - # Calculate dissipation times DT50 and DT90 + # Calculate dissipation times DT50 and DT90 and formation fractions parms.all = c(fit$par, parms.fixed) fit$distimes <- data.frame(DT50 = rep(NA, length(obs_vars)), DT90 = rep(NA, length(obs_vars)), row.names = obs_vars) + fit$ff <- vector() + fit$SFORB <- vector() for (obs_var in obs_vars) { - type = names(mkinmod$map[[obs_var]])[1] - if (type == "SFO") { - k_names = grep(paste("k", obs_var, sep="_"), names(parms.all), value=TRUE) - k_tot = sum(parms.all[k_names]) - DT50 = log(2)/k_tot - DT90 = log(10)/k_tot + type = names(mkinmod$map[[obs_var]])[1] + if (type == "SFO") { + k_names = grep(paste("k", obs_var, sep="_"), names(parms.all), value=TRUE) + k_tot = sum(parms.all[k_names]) + DT50 = log(2)/k_tot + DT90 = log(10)/k_tot + for (k_name in k_names) + { + fit$ff[[sub("k_", "", k_name)]] = parms.all[[k_name]] / k_tot } - if (type == "FOMC") { - alpha = parms.all["alpha"] - beta = parms.all["beta"] - DT50 = beta * (2^(1/alpha) - 1) - DT90 = beta * (10^(1/alpha) - 1) + } + if (type == "FOMC") { + alpha = parms.all["alpha"] + beta = parms.all["beta"] + DT50 = beta * (2^(1/alpha) - 1) + DT90 = beta * (10^(1/alpha) - 1) + } + if (type == "DFOP") { + k1 = parms.all["k1"] + k2 = parms.all["k2"] + g = parms.all["g"] + f <- function(t, x) { + fraction <- g * exp( - k1 * t) + (1 - g) * exp( - k2 * t) + (fraction - (1 - x/100))^2 } - if (type == "SFORB") { - # FOCUS kinetics (2006), p. 60 f - k_out_names = grep(paste("k", obs_var, "free", sep="_"), names(parms.all), value=TRUE) - k_out_names = setdiff(k_out_names, paste("k", obs_var, "free", "bound", sep="_")) - k_1output = sum(parms.all[k_out_names]) - k_12 = parms.all[paste("k", obs_var, "free", "bound", sep="_")] - k_21 = parms.all[paste("k", obs_var, "bound", "free", sep="_")] - - sqrt_exp = sqrt(1/4 * (k_12 + k_21 + k_1output)^2 + k_12 * k_21 - (k_12 + k_1output) * k_21) - b1 = 0.5 * (k_12 + k_21 + k_1output) + sqrt_exp - b2 = 0.5 * (k_12 + k_21 + k_1output) - sqrt_exp - - SFORB_fraction = function(t) { - ((k_12 + k_21 - b1)/(b2 - b1)) * exp(-b1 * t) + - ((k_12 + k_21 - b2)/(b1 - b2)) * exp(-b2 * t) - } - f_50 <- function(t) (SFORB_fraction(t) - 0.5)^2 - max_DT <- 1000 - DT50.o <- optimize(f_50, c(0.01, max_DT))$minimum - if (abs(DT50.o - max_DT) < 0.01) DT50 = NA else DT50 = DT50.o - f_90 <- function(t) (SFORB_fraction(t) - 0.1)^2 - DT90.o <- optimize(f_90, c(0.01, 1000))$minimum - if (abs(DT90.o - max_DT) < 0.01) DT90 = NA else DT90 = DT90.o + DTmax <- 1000 + DT50.o <- optimize(f, c(0.001, DTmax), x=50)$minimum + DT50 = ifelse(DTmax - DT50.o < 0.1, NA, DT50.o) + DT90.o <- optimize(f, c(0.001, DTmax), x=90)$minimum + DT90 = ifelse(DTmax - DT90.o < 0.1, NA, DT90.o) + } + if (type == "HS") { + k1 = parms.all["k1"] + k2 = parms.all["k2"] + tb = parms.all["tb"] + DTx <- function(x) { + DTx.a <- (log(100/(100 - x)))/k1 + DTx.b <- tb + (log(100/(100 - x)) - k1 * tb)/k2 + if (DTx.a < tb) DTx <- DTx.a + else DTx <- DTx.b + return(DTx) } - fit$distimes[obs_var, ] = c(DT50, DT90) + DT50 <- DTx(50) + DT90 <- DTx(90) + } + # Back-calculation of formation fractions in case of nonlinear parent kinetics + if (type %in% c("FOMC", "DFOP", "HS")) { + ff_names = names(mkinmod$ff) + for (ff_name in ff_names) + { + fit$ff[[paste(obs_var, ff_name, sep="_")]] = + eval(parse(text = mkinmod$ff[ff_name]), as.list(parms.all)) + } + fit$ff[[paste(obs_var, "sink", sep="_")]] = 1 - sum(fit$ff) + } + if (type == "SFORB") { + # FOCUS kinetics (2006), p. 60 f + k_out_names = grep(paste("k", obs_var, "free", sep="_"), names(parms.all), value=TRUE) + k_out_names = setdiff(k_out_names, paste("k", obs_var, "free", "bound", sep="_")) + k_1output = sum(parms.all[k_out_names]) + k_12 = parms.all[paste("k", obs_var, "free", "bound", sep="_")] + k_21 = parms.all[paste("k", obs_var, "bound", "free", sep="_")] + + sqrt_exp = sqrt(1/4 * (k_12 + k_21 + k_1output)^2 + k_12 * k_21 - (k_12 + k_1output) * k_21) + b1 = 0.5 * (k_12 + k_21 + k_1output) + sqrt_exp + b2 = 0.5 * (k_12 + k_21 + k_1output) - sqrt_exp + + SFORB_fraction = function(t) { + ((k_12 + k_21 - b1)/(b2 - b1)) * exp(-b1 * t) + + ((k_12 + k_21 - b2)/(b1 - b2)) * exp(-b2 * t) + } + f_50 <- function(t) (SFORB_fraction(t) - 0.5)^2 + max_DT <- 1000 + DT50.o <- optimize(f_50, c(0.01, max_DT))$minimum + if (abs(DT50.o - max_DT) < 0.01) DT50 = NA else DT50 = DT50.o + f_90 <- function(t) (SFORB_fraction(t) - 0.1)^2 + DT90.o <- optimize(f_90, c(0.01, max_DT))$minimum + if (abs(DT90.o - max_DT) < 0.01) DT90 = NA else DT90 = DT90.o + for (k_out_name in k_out_names) + { + fit$ff[[sub("k_", "", k_out_name)]] = parms.all[[k_out_name]] / k_1output + } + # Return the eigenvalues for comparison with DFOP rate constants + fit$SFORB[[paste(obs_var, "b1", sep="_")]] = b1 + fit$SFORB[[paste(obs_var, "b2", sep="_")]] = b2 + } + fit$distimes[obs_var, ] = c(DT50, DT90) } # Collect observed, predicted and residuals @@ -217,25 +410,74 @@ mkinfit <- function(mkinmod, observed, data$residual <- data$observed - data$predicted data$variable <- ordered(data$variable, levels = obs_vars) fit$data <- data[order(data$variable, data$time), ] + fit$atol <- atol class(fit) <- c("mkinfit", "modFit") return(fit) } -summary.mkinfit <- function(object, data = TRUE, distimes = TRUE, cov = FALSE,...) { - ans <- FME:::summary.modFit(object, cov = cov) +summary.mkinfit <- function(object, data = TRUE, distimes = TRUE, ff = TRUE, cov = FALSE,...) { + param <- object$par + pnames <- names(param) + p <- length(param) + covar <- try(solve(0.5*object$hessian), silent = TRUE) # unscaled covariance + if (!is.numeric(covar)) { + message <- "Cannot estimate covariance; system is singular" + warning(message) + covar <- matrix(data = NA, nrow = p, ncol = p) + } else message <- "ok" + + rownames(covar) <- colnames(covar) <-pnames + rdf <- object$df.residual + resvar <- object$ssr / rdf + se <- sqrt(diag(covar) * resvar) + names(se) <- pnames + tval <- param / se + modVariance <- object$ssr / length(object$residuals) + + if (!all(object$start$lower >=0)) { + message <- "Note that the one-sided t-test may not be appropriate if + parameter values below zero are possible." + warning(message) + } else message <- "ok" + + param <- cbind(param, se, tval, pt(tval, rdf, lower.tail = FALSE)) + dimnames(param) <- list(pnames, c("Estimate", "Std. Error", + "t value", "Pr(>t)")) + if(cov) + ans <- list(residuals = object$residuals, + residualVariance = resvar, + sigma = sqrt(resvar), + modVariance = modVariance, + df = c(p, rdf), cov.unscaled = covar, + cov.scaled = covar * resvar, + info = object$info, niter = object$iterations, + stopmess = message, + par = param) + else + ans <- list(residuals = object$residuals, + residualVariance = resvar, + sigma = sqrt(resvar), + modVariance = modVariance, + df = c(p, rdf), + info = object$info, niter = object$iterations, + stopmess = message, + par = param) + ans$diffs <- object$diffs if(data) ans$data <- object$data ans$start <- object$start ans$fixed <- object$fixed ans$errmin <- object$errmin if(distimes) ans$distimes <- object$distimes + if(ff) ans$ff <- object$ff + if(length(object$SFORB) != 0) ans$SFORB <- object$SFORB class(ans) <- c("summary.mkinfit", "summary.modFit") return(ans) } # Expanded from print.summary.modFit -print.summary.mkinfit <- function(x, digits = max(3, getOption("digits") - 3), ...) { +print.summary.mkinfit <- function(x, digits = max(3, getOption("digits") - 3), tval = TRUE, ...) { cat("\nEquations:\n") print(noquote(as.character(x[["diffs"]]))) df <- x$df @@ -249,7 +491,11 @@ print.summary.mkinfit <- function(x, digits = max(3, getOption("digits") - 3), . else print(x$fixed) cat("\nOptimised parameters:\n") - printCoefmat(x$par, digits = digits, ...) + if (tval) printCoefmat(x$par, digits = digits, ...) + else { + printCoefmat(x$par[,c(1,2,4)], cs.in = c(1,2), tst.ind = integer(0), + P.values = TRUE, has.Pvalue = TRUE, digits = digits, ...) + } cat("\nResidual standard error:", format(signif(x$sigma, digits)), "on", rdf, "degrees of freedom\n") @@ -260,10 +506,22 @@ print.summary.mkinfit <- function(x, digits = max(3, getOption("digits") - 3), . printdistimes <- !is.null(x$distimes) if(printdistimes){ - cat("\nEstimated disappearance times\n") + cat("\nEstimated disappearance times:\n") print(x$distimes, digits=digits,...) } + printff <- !is.null(x$ff) + if(printff){ + cat("\nEstimated formation fractions:\n") + print(data.frame(ff = x$ff), digits=digits,...) + } + + printSFORB <- !is.null(x$SFORB) + if(printSFORB){ + cat("\nEstimated Eigenvalues of SFORB model(s):\n") + print(x$SFORB, digits=digits,...) + } + printcor <- !is.null(x$cov.unscaled) if (printcor){ Corr <- cov2cor(x$cov.unscaled) diff --git a/R/mkinmod.R b/R/mkinmod.R index 643e855..31c778c 100644 --- a/R/mkinmod.R +++ b/R/mkinmod.R @@ -1,3 +1,23 @@ +# $Id: mkinmod.R 71 2010-09-12 01:13:36Z jranke $ + +# Copyright (C) 2010 Johannes Ranke +# Contact: mkin-devel@lists.berlios.de + +# This file is part of the R package mkin + +# mkin is free software: you can redistribute it and/or modify it under the +# terms of the GNU General Public License as published by the Free Software +# Foundation, either version 3 of the License, or (at your option) any later +# version. + +# This program is distributed in the hope that it will be useful, but WITHOUT +# ANY WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS +# FOR A PARTICULAR PURPOSE. See the GNU General Public License for more +# details. + +# You should have received a copy of the GNU General Public License along with +# this program. If not, see + mkinmod <- function(...) { spec <- list(...) @@ -5,22 +25,36 @@ mkinmod <- function(...) # The returned model will be a list of character vectors, containing # differential equations, parameter names and a mapping from model variables - # to observed variables + # to observed variables. If possible, a matrix representation of the + # differential equations is included parms <- vector() diffs <- vector() map <- list() + if(spec[[1]]$type %in% c("FOMC", "DFOP", "HS")) { + mat = FALSE + if(!is.null(spec[[1]]$to)) { + message <- paste("Only constant formation fractions over time are implemented.", + "Depending on the reason for the time dependence of degradation, this may be unrealistic", + sep="\n") + warning(message) + } else message <- "ok" + } else mat = TRUE # Establish list of differential equations for (varname in obs_vars) { - if(is.null(spec[[varname]]$type)) stop("Every argument to mkinmod must be a list containing a type component") - if(!spec[[varname]]$type %in% c("SFO", "FOMC", "SFORB")) stop("Available types are SFO, FOMC and SFORB only") + if(is.null(spec[[varname]]$type)) stop( + "Every argument to mkinmod must be a list containing a type component") + if(!spec[[varname]]$type %in% c("SFO", "FOMC", "DFOP", "HS", "SFORB")) stop( + "Available types are SFO, FOMC, DFOP, HS and SFORB only") new_parms <- vector() # New (sub)compartments (boxes) needed for the model type new_boxes <- switch(spec[[varname]]$type, SFO = varname, FOMC = varname, + DFOP = varname, + HS = varname, SFORB = paste(varname, c("free", "bound"), sep="_") ) map[[varname]] <- new_boxes @@ -29,25 +63,64 @@ mkinmod <- function(...) # Start a new differential equation for each new box new_diffs <- paste("d_", new_boxes, " =", sep="") - # Construct terms for transfer to sink and add if appropriate + # Turn on sink if not specified otherwise if(is.null(spec[[varname]]$sink)) spec[[varname]]$sink <- TRUE + + # Construct and add FOMC term and add FOMC parameters if needed + if(spec[[varname]]$type == "FOMC") { + if(match(varname, obs_vars) != 1) { + stop("Type FOMC is only possible for the first compartment, which is assumed to be the source compartment") + } + if(spec[[varname]]$sink == FALSE) { + stop("Turning off the sink for the FOMC model is not implemented") + } + # From p. 53 of the FOCUS kinetics report + nonlinear_term <- paste("(alpha/beta) * ((time/beta) + 1)^-1 *", new_boxes[[1]]) + new_diffs[[1]] <- paste(new_diffs[[1]], "-", nonlinear_term) + new_parms <- c("alpha", "beta") + ff <- vector() + } + + # Construct and add DFOP term and add DFOP parameters if needed + if(spec[[varname]]$type == "DFOP") { + if(match(varname, obs_vars) != 1) { + stop("Type DFOP is only possible for the first compartment, which is assumed to be the source compartment") + } + if(spec[[varname]]$sink == FALSE) { + stop("Turning off the sink for the DFOP model is not implemented") + } + # From p. 57 of the FOCUS kinetics report + nonlinear_term <- paste("((k1 * g * exp(-k1 * time) + k2 * (1 - g) * exp(-k2 * time)) / (g * exp(-k1 * time) + (1 - g) * exp(-k2 * time))) *", new_boxes[[1]]) + new_diffs[[1]] <- paste(new_diffs[[1]], "-", nonlinear_term) + new_parms <- c("k1", "k2", "g") + ff <- vector() + } + + # Construct and add HS term and add HS parameters if needed + if(spec[[varname]]$type == "HS") { + if(match(varname, obs_vars) != 1) { + stop("Type HS is only possible for the first compartment, which is assumed to be the source compartment") + } + if(spec[[varname]]$sink == FALSE) { + stop("Turning off the sink for the HS model is not implemented") + } + # From p. 55 of the FOCUS kinetics report + nonlinear_term <- paste("ifelse(time <= tb, k1, k2)", "*", new_boxes[[1]]) + new_diffs[[1]] <- paste(new_diffs[[1]], "-", nonlinear_term) + new_parms <- c("k1", "k2", "tb") + ff <- vector() + } + + # Construct terms for transfer to sink and add if appropriate + if(spec[[varname]]$sink) { - # Add first-order sink term to first (or only) box for SFO and SFORB models + # Add first-order sink term to first (or only) box for SFO and SFORB if(spec[[varname]]$type %in% c("SFO", "SFORB")) { k_compound_sink <- paste("k", new_boxes[[1]], "sink", sep="_") sink_term <- paste("-", k_compound_sink, "*", new_boxes[[1]]) new_diffs[[1]] <- paste(new_diffs[[1]], sink_term) new_parms <- k_compound_sink } - if(spec[[varname]]$type == "FOMC") { - if(match(varname, obs_vars) != 1) { - stop("Type FOMC is only allowed for the first compartment, which is assumed to be the source compartment") - } - # From p. 53 of the FOCUS kinetics report - fomc_term <- paste("(alpha/beta) * ((time/beta) + 1)^-1 *", new_boxes[[1]]) - new_diffs[[1]] <- paste(new_diffs[[1]], "-", fomc_term) - new_parms <- c("alpha", "beta") - } } # Add reversible binding if appropriate @@ -66,7 +139,6 @@ mkinmod <- function(...) names(new_diffs) <- new_boxes diffs <- c(diffs, new_diffs) } - # Transfer between compartments for (varname in obs_vars) { to <- spec[[varname]]$to @@ -74,6 +146,8 @@ mkinmod <- function(...) origin_box <- switch(spec[[varname]]$type, SFO = varname, FOMC = varname, + DFOP = varname, + HS = varname, SFORB = paste(varname, "free", sep="_")) fraction_left <- NULL for (target in to) { @@ -82,27 +156,63 @@ mkinmod <- function(...) SFORB = paste(target, "free", sep="_")) if(spec[[varname]]$type %in% c("SFO", "SFORB")) { k_from_to <- paste("k", origin_box, target_box, sep="_") - diffs[[origin_box]] <- paste(diffs[[origin_box]], "-", k_from_to, "*", origin_box) - diffs[[target_box]] <- paste(diffs[[target_box]], "+", k_from_to, "*", origin_box) + diffs[[origin_box]] <- paste(diffs[[origin_box]], "-", + k_from_to, "*", origin_box) + diffs[[target_box]] <- paste(diffs[[target_box]], "+", + k_from_to, "*", origin_box) parms <- c(parms, k_from_to) } - if(spec[[varname]]$type == "FOMC") { + if(spec[[varname]]$type %in% c("FOMC", "DFOP", "HS")) { fraction_to_target = paste("f_to", target, sep="_") - fraction_not_to_target = paste("(1 - ", fraction_to_target, ")", sep="") + fraction_not_to_target = paste("(1 - ", fraction_to_target, ")", + sep="") if(is.null(fraction_left)) { fraction_really_to_target = fraction_to_target fraction_left = fraction_not_to_target } else { - fraction_really_to_target = paste(fraction_left, " * ", fraction_to_target, sep="") - fraction_left = paste(fraction_left, " * ", fraction_not_to_target, sep="") + fraction_really_to_target = paste(fraction_left, " * ", + fraction_to_target, sep="") + fraction_left = paste(fraction_left, " * ", + fraction_not_to_target, sep="") } - diffs[[target_box]] <- paste(diffs[[target_box]], "+", fraction_really_to_target, "*", fomc_term) + ff[target_box] = fraction_really_to_target + diffs[[target_box]] <- paste(diffs[[target_box]], "+", + ff[target_box], "*", nonlinear_term) parms <- c(parms, fraction_to_target) } } } } model <- list(diffs = diffs, parms = parms, map = map) + + # Create coefficient matrix if appropriate + if (mat) { + boxes <- names(diffs) + n <- length(boxes) + m <- matrix(nrow=n, ncol=n, dimnames=list(boxes, boxes)) + for (from in boxes) { + for (to in boxes) { + if (from == to) { + k.candidate = paste("k", from, c(boxes, "sink"), sep="_") + k.candidate = sub("free.*bound", "free_bound", k.candidate) + k.candidate = sub("bound.*free", "bound_free", k.candidate) + k.effective = intersect(model$parms, k.candidate) + m[from,to] = ifelse(length(k.effective) > 0, + paste("-", k.effective, collapse = " "), "0") + } else { + k.candidate = paste("k", from, to, sep="_") + k.candidate = sub("free.*bound", "free_bound", k.candidate) + k.candidate = sub("bound.*free", "bound_free", k.candidate) + k.effective = intersect(model$parms, k.candidate) + m[to, from] = ifelse(length(k.effective) > 0, + k.effective, "0") + } + } + } + model$coefmat <- m + } + + if (exists("ff")) model$ff = ff class(model) <- "mkinmod" invisible(model) } diff --git a/R/mkinplot.R b/R/mkinplot.R index d2880c0..d665bc2 100644 --- a/R/mkinplot.R +++ b/R/mkinplot.R @@ -1,5 +1,6 @@ -mkinplot <- function(fit, xlab = "Time", ylab = "Observed", xlim = range(fit$data$time), ylim = range(fit$data$observed, na.rm = TRUE), ...) +mkinplot <- function(fit, xlab = "Time", ylab = "Observed", xlim = range(fit$data$time), ylim = range(fit$data$observed, na.rm = TRUE), legend = TRUE, ...) { + solution = fit$solution fixed <- fit$fixed$value names(fixed) <- rownames(fit$fixed) parms.all <- c(fit$par, fixed) @@ -16,12 +17,60 @@ mkinplot <- function(fit, xlab = "Time", ylab = "Observed", xlim = range(fit$dat rownames(subset(fit$fixed, type == "deparm"))) odeparms <- parms.all[odenames] - # Solve the ode - out <- ode( - y = odeini, - times = outtimes, - func = fit$mkindiff, - parms = odeparms) + # Solve the system + evalparse <- function(string) + { + eval(parse(text=string), as.list(c(odeparms, odeini))) + } + if (solution == "analytical") { + parent.type = names(fit$map[[1]])[1] + parent.name = names(fit$diffs)[[1]] + o <- switch(parent.type, + SFO = SFO.solution(outtimes, + evalparse(parent.name), + evalparse(paste("k", parent.name, "sink", sep="_"))), + FOMC = FOMC.solution(outtimes, + evalparse(parent.name), + evalparse("alpha"), evalparse("beta")), + DFOP = DFOP.solution(outtimes, + evalparse(parent.name), + evalparse("k1"), evalparse("k2"), + evalparse("g")), + HS = HS.solution(outtimes, + evalparse(parent.name), + evalparse("k1"), evalparse("k2"), + evalparse("tb")), + SFORB = SFORB.solution(outtimes, + evalparse(parent.name), + evalparse(paste("k", parent.name, "free_bound", sep="_")), + evalparse(paste("k", parent.name, "bound_free", sep="_")), + evalparse(paste("k", parent.name, "free_sink", sep="_"))) + ) + out <- cbind(outtimes, o) + dimnames(out) <- list(outtimes, c("time", parent.name)) + } + if (solution == "eigen") { + coefmat.num <- matrix(sapply(as.vector(fit$coefmat), evalparse), + nrow = length(odeini)) + e <- eigen(coefmat.num) + c <- solve(e$vectors, odeini) + f.out <- function(t) { + e$vectors %*% diag(exp(e$values * t), nrow=length(odeini)) %*% c + } + o <- matrix(mapply(f.out, outtimes), + nrow = length(odeini), ncol = length(outtimes)) + dimnames(o) <- list(names(odeini), NULL) + out <- cbind(time = outtimes, t(o)) + } + if (solution == "deSolve") { + out <- ode( + y = odeini, + times = outtimes, + func = fit$mkindiff, + parms = odeparms, + atol = fit$atol + ) + } # Output transformation for models with unobserved compartments like SFORB out_transformed <- data.frame(time = out[,"time"]) @@ -36,14 +85,16 @@ mkinplot <- function(fit, xlab = "Time", ylab = "Observed", xlim = range(fit$dat # Plot the data and model output plot(0, type="n", xlim = xlim, ylim = ylim, - xlab = xlab, ylab = ylab, ...) - col_obs <- pch_obs <- 1:length(fit$map) - names(col_obs) <- names(pch_obs) <- names(fit$map) - for (obs_var in names(fit$map)) { - points(subset(fit$data, variable == obs_var, c(time, observed)), - pch = pch_obs[obs_var], col = col_obs[obs_var]) - } - matlines(out_transformed$time, out_transformed[-1]) - legend("topright", inset=c(0.05, 0.05), legend=names(fit$map), + xlab = xlab, ylab = ylab, ...) + col_obs <- pch_obs <- 1:length(fit$map) + names(col_obs) <- names(pch_obs) <- names(fit$map) + for (obs_var in names(fit$map)) { + points(subset(fit$data, variable == obs_var, c(time, observed)), + pch = pch_obs[obs_var], col = col_obs[obs_var]) + } + matlines(out_transformed$time, out_transformed[-1]) + if (legend == TRUE) { + legend("topright", inset=c(0.05, 0.05), legend=names(fit$map), col=col_obs, pch=pch_obs, lty=1:length(pch_obs)) + } } diff --git a/R/mkinresplot.R b/R/mkinresplot.R new file mode 100644 index 0000000..bede5f7 --- /dev/null +++ b/R/mkinresplot.R @@ -0,0 +1,54 @@ +# $Id: $ + +# Copyright (C) 2008-2011 Katrin Lindenberger and Johannes Ranke +# Contact: mkin-devel@lists.berlios.de + +# This file is part of the R package mkin + +# mkin is free software: you can redistribute it and/or modify it under the +# terms of the GNU General Public License as published by the Free Software +# Foundation, either version 3 of the License, or (at your option) any later +# version. + +# This program is distributed in the hope that it will be useful, but WITHOUT +# ANY WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS +# FOR A PARTICULAR PURPOSE. See the GNU General Public License for more +# details. + +# You should have received a copy of the GNU General Public License along with +# this program. If not, see + +mkinresplot <- function (object, obs_vars = vector(), + xlab = "Time [days]", ylab = "Residual [% of applied radioactivity]", + maxabs = "auto", legend= TRUE, lpos = "topright", ...) +{ + obs_vars_all <- as.character(unique(object$data$variable)) + + if (length(obs_vars) > 0){ + vars <- intersect(obs_vars_all, obs_vars) + } else vars <- obs_vars_all + + residuals <- subset(object$data, variable %in% vars, residual) + + if (maxabs == "auto") maxabs = max(abs(residuals), na.rm = TRUE) + + col_obs <- pch_obs <- 1:length(vars) + names(col_obs) <- names(pch_obs) <- vars + + plot(0, xlab = xlab, ylab = ylab, + xlim = c(0, 1.1 * max(object$data$time)), + ylim = c(-1.2 * maxabs, 1.2 * maxabs), ...) + + for(var in vars){ + residuals_plot <- subset(object$data, variable == var, c("time", "residual")) + points(residuals_plot, pch = pch_obs[var], col = col_obs[var]) + } + + abline(h = 0, lty = 2) + title(paste("Residuals of mkin fit"), font.main = 1) + + if (legend == TRUE) { + legend(lpos, inset = c(0.05, 0.05), legend = vars, + col = col_obs, pch = pch_obs) + } +} diff --git a/R/mkinstart.R b/R/mkinstart.R new file mode 100644 index 0000000..46e5bed --- /dev/null +++ b/R/mkinstart.R @@ -0,0 +1,23 @@ +mkinstart <- function(model, data, mode = "auto") +{ + if (class(model) != "mkinmod") stop("The first argument must be a model of class mkinmod") + names <- model$parms + observed <- names(model$map) + if(!all(observed %in% levels(data$name))) stop("The data must contain the observed variables used in the model") + for (obs in observed) + { + tmp <- subset(data, name == obs) + max <- tmp[which.max(tmp$value), ] + type = names(model$map[[obs]])[[1]] + kinmodel <- ifelse(type == "SFORB", "DFOP", type) + tmp.longdata <- subset(data, name == obs & time >= max$time) + tmp.widedata <- mkin_long_to_wide(tmp.longdata, outtime = "t") + names(tmp.widedata) <- c("t", "parent") + tmp.fit <- kinfit( + kindata = tmp.widedata, + kinmodels = kinmodel, + parent.0.user = max$value) + if(class(tmp.fit[[kinmodel]]) == "try-error") stop(paste("Automatic generation of starting parameters failed\nkinfit failed to find a", kinmodel, "fit for", obs)) + tmp.results <- kinresults(tmp.fit) + } +} diff --git a/inst/GUI/.RData b/inst/GUI/.RData new file mode 100644 index 0000000..2e82ef7 Binary files /dev/null and b/inst/GUI/.RData differ diff --git a/inst/GUI/.Rhistory b/inst/GUI/.Rhistory new file mode 100644 index 0000000..0704745 --- /dev/null +++ b/inst/GUI/.Rhistory @@ -0,0 +1,3 @@ +require(gWidgetsWWW) +localServerStart("simple.R") +quit("yes") diff --git a/inst/GUI/gdf-test.R b/inst/GUI/gdf-test.R new file mode 100644 index 0000000..b1ec20a --- /dev/null +++ b/inst/GUI/gdf-test.R @@ -0,0 +1,12 @@ +w <- gwindow("gdf test") +g <- ggroup(horizontal=FALSE, cont=w) +d <- gdf(data.frame(a=c(1.1, 2.2, 3.3), b= c("one", "two", "three"), stringsAsFactors=FALSE), + name = "Test for editing character columns", cont=g) +size(d) <- c(400,400) +gbutton("Change [1,2]", handler=function(h,...) { + d[1,2] <- "test" +}, container=g) +gbutton("Value of [1,2]", handler=function(h,...) { + galert(d[1,2], parent=d) +}, cont=g) +visible(w) <- TRUE diff --git a/inst/GUI/simple-Gtk.R b/inst/GUI/simple-Gtk.R new file mode 100644 index 0000000..8affdcc --- /dev/null +++ b/inst/GUI/simple-Gtk.R @@ -0,0 +1,33 @@ +# Work in progress - simple Gtk2 GUI for mkin +require(gWidgets) +options("guiToolkit"="RGtk2") + +w <- gwindow("Simple R GUI for kinetic evaluations", + width=800, height=500) + +# Project definition expanding group +pr <- gexpandgroup("Project definition", container=w) + +n.observed <- 1 +max.n.observed <- 9 +observed.names = c("parent", paste("M", 1:(max.n.observed - 1), sep="")) + +prg <- ggroup(horizontal=FALSE, cont = w) +prl <- glayout(cont = prg) +prl[1,1] <- glabel("Number of observed variables", cont=prl) +prl[1,2] <- (n.observed.gw = gcombobox( + 1:max.n.observed, + handler = function(h, ...) { + n.observed <- svalue(n.observed.gw) + visible(observed.gw) <- c( + rep(TRUE, svalue(n.observed)), + rep(FALSE, max.n.observed - n.observed)) + }, + cont=prl)) + +observed.gw <- gdf( + items = data.frame(Index = 1:max.n.observed, + Name = observed.names, stringsAsFactors=FALSE), + name = "Names of observed variables", + cont=prg) + diff --git a/inst/GUI/simple.R b/inst/GUI/simple.R new file mode 100644 index 0000000..c187414 --- /dev/null +++ b/inst/GUI/simple.R @@ -0,0 +1,68 @@ +# Work in progress - simple GUI for mkin +w <- gwindow('Simple R GUI for kinetic evaluations', visible=FALSE) +# Project definition {{{ +pr <- gexpandgroup("Project", cont=w) + +n.observed <- 1 +max.n.observed <- 9 +observed.names = c("parent", paste("M", 1:(max.n.observed - 1), sep="")) + +prg <- ggroup(horizontal=FALSE, cont = pr) +prl <- glayout(cont = prg) +prl[1,1] <- glabel("Number of observed variables", cont=prl) +prl[1,2] <- (n.observed.gw = gcombobox( + 1:max.n.observed, + handler = function(h, ...) { + n.observed <<- svalue(n.observed.gw) + filter.expression <- paste("^[1-", n.observed, "]$", sep="") + observed.gw$filter("Index", filter.expression) + }, + cont=prl)) + +observed.gw <- gdf( + items = data.frame(Index = 1:max.n.observed, + Name = observed.names, stringsAsFactors=FALSE), + name = "Names of observed variables", + width = 500, height=250, cont=prg) + +addSpace(prg, 15) +prf <- gfile("Project file in binary R format (preferably use .RData as extension)", + container = prg) +addSpring(prg) +addSpace(prg, 15) +pr.ok <- gbutton("save", + handler=function(h,...) { + galert(svalue(prf), parent=w) + }, container=prg) + +gbutton("ok", handler = function(h, ...) { + observed <- observed.gw[1:n.observed,2] + save(observed, file="observed.RData") + visible(pr) <- FALSE + }, + cont=prg +) + +visible(pr) <- TRUE +# }}} + +# Dataset definition +ds <- gexpandgroup("Datasets", cont=w) +s <- gdf(data.frame( Author = c("Meier"), Year = "3", Title = "4"), + name = "Studies", +cont=ds) + +size(s) <- c(800,200) +visible(ds) <- TRUE + +# Model definition +ms <- gexpandgroup("Models", cont=w) +visible(ms) <- FALSE + +# Evaluation window +mw <- gframe("Evaluations", cont=w) + +# Status bar +gstatusbar("Powered by gWidgetsWWW", cont = w) +visible(w) <- TRUE +# vim: set foldmethod=marker: diff --git a/inst/GUI/test.R b/inst/GUI/test.R new file mode 100644 index 0000000..e33e077 --- /dev/null +++ b/inst/GUI/test.R @@ -0,0 +1,17 @@ +require(gWidgetsWWW) +localServerStart("simple.R") + +localServerStart("gdf-test.R") +localServerStart("gdf-test-john.R") + +localServerStart("Examples/ex-actions.R", package="gWidgetsWWW") +localServerStart("Examples/ex-add-widget-dynamically.R", package="gWidgetsWWW") +localServerStart("Examples/ex-clt.R", package="gWidgetsWWW") +localServerStart("Examples/ex-form.R", package="gWidgetsWWW") +localServerStart("Examples/ex-gcombobox.R", package="gWidgetsWWW") +localServerStart("Examples/ex-gtable.R", package="gWidgetsWWW") 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data} %%VignetteDepends{FME} %%\usepackage{Sweave} @@ -78,7 +79,7 @@ barrier for \RR{} newcomers. \subsection{Data format} The following listing shows example dataset C from the FOCUS kinetics -report as distributed with the \Rpackage{kinfit} package +report as distributed with the \Rpackage{mkin} package <>= library("mkin") @@ -101,8 +102,9 @@ as shown in the following listing <>= example_data <- data.frame( + name = rep("parent", 9), time = c(0, 1, 3, 7, 14, 28, 63, 91, 119), - parent = c(85.1, 57.9, 29.9, 14.6, 9.7, 6.6, 4, 3.9, 0.6) + value = c(85.1, 57.9, 29.9, 14.6, 9.7, 6.6, 4, 3.9, 0.6) ) @ @@ -122,12 +124,23 @@ SFORB_SFO <- mkinmod( m1 = list(type = "SFO")) @ +The model definitions given above define sets of linear first-order ordinary +differential equations. In these cases, a coefficient matrix is also returned. + +Other models that include time on the right-hand side of the differential +equation are the first-order multi-compartment (FOMC) model and the +Hockey-Stick (HS) model. At present, only the FOMC model can only be used, and +only for the parent compound. + \subsection{Fitting the model} Then the model parameters should be fitted to the data. The function \Robject{mkinfit} internally creates a cost function using \Robject{modCost} from the \Rpackage{FME} package and the produces a fit using \Robject{modFit} -from the same package. +from the same package. In cases of linear first-order differential +equations, the solution used for calculating the cost function is based +on the fundamental system of the coefficient matrix, as proposed by +\citet{bates88}. <>= # Do not show significance stars as they interfere with vignette generation @@ -136,8 +149,10 @@ SFO.fit <- mkinfit(SFO, FOCUS_2006_C) summary(SFO.fit) SFORB.fit <- mkinfit(SFORB, FOCUS_2006_C) summary(SFORB.fit) -SFO_SFO.fit <- mkinfit(SFO_SFO, FOCUS_2006_D) -summary(SFO_SFO.fit) +SFO_SFO.fit <- mkinfit(SFO_SFO, FOCUS_2006_D, plot=TRUE) +summary(SFO_SFO.fit, data=FALSE) +SFORB_SFO.fit <- mkinfit(SFORB_SFO, FOCUS_2006_D, plot=TRUE) +summary(SFORB_SFO.fit, data=FALSE) @ \bibliographystyle{plainnat} diff --git a/inst/doc/mkin.pdf b/inst/doc/mkin.pdf index 4d2e1d1..f963d1e 100644 Binary files a/inst/doc/mkin.pdf and b/inst/doc/mkin.pdf differ diff --git a/inst/doc/references.bib b/inst/doc/references.bib index b158eeb..24672e2 100644 --- a/inst/doc/references.bib +++ b/inst/doc/references.bib @@ -53,3 +53,10 @@ address = {Piacenza}, pages = {916--923} } + +@Book{ bates88, + title = {Nonlinear regression and its applications}, + author = {D. Bates and D. Watts}, + year = {1988}, + publisher = {Wiley-Interscience} +} diff --git a/inst/unitTests/runit.mkinfit.R b/inst/unitTests/runit.mkinfit.R index df09cc6..831c069 100644 --- a/inst/unitTests/runit.mkinfit.R +++ b/inst/unitTests/runit.mkinfit.R @@ -1,3 +1,23 @@ +# $Id: runit.mkinfit.R 68 2010-09-09 22:40:04Z jranke $ + +# Copyright (C) 2010 Johannes Ranke +# Contact: mkin-devel@lists.berlios.de + +# This file is part of the R package mkin + +# mkin is free software: you can redistribute it and/or modify it under the +# terms of the GNU General Public License as published by the Free Software +# Foundation, either version 3 of the License, or (at your option) any later +# version. + +# This program is distributed in the hope that it will be useful, but WITHOUT +# ANY WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS +# FOR A PARTICULAR PURPOSE. See the GNU General Public License for more +# details. + +# You should have received a copy of the GNU General Public License along with +# this program. If not, see + test.mkinmod.schaefer07_complex_example <- function() { schaefer07_complex_model <- mkinmod( @@ -17,16 +37,16 @@ test.mkinmod.schaefer07_complex_example <- function() r$mkin <- c( k_parent, s$distimes["parent", "DT50"], - k_parent_A1/k_parent, + s$ff["parent_A1"], sum(k_A1_sink, k_A1_A2), s$distimes["A1", "DT50"], - k_parent_B1/k_parent, + s$ff["parent_B1"], k_B1_sink, s$distimes["B1", "DT50"], - k_parent_C1/k_parent, + s$ff["parent_C1"], k_C1_sink, s$distimes["C1", "DT50"], - k_A1_A2/(k_A1_A2 + k_A1_sink), + s$ff["A1_A2"], k_A2_sink, s$distimes["A2", "DT50"]) r$means <- (r$KinGUI + r$ModelMaker)/2 diff --git a/inst/unitTests/runit.mkinmod.R b/inst/unitTests/runit.mkinmod.R index 44d9ffb..a0e8996 100644 --- a/inst/unitTests/runit.mkinmod.R +++ b/inst/unitTests/runit.mkinmod.R @@ -1,3 +1,23 @@ +# $Id: runit.mkinmod.R 64 2010-09-01 13:33:51Z jranke $ + +# Copyright (C) 2010 Johannes Ranke +# Contact: mkin-devel@lists.berlios.de + +# This file is part of the R package mkin + +# mkin is free software: you can redistribute it and/or modify it under the +# terms of the GNU General Public License as published by the Free Software +# Foundation, either version 3 of the License, or (at your option) any later +# version. + +# This program is distributed in the hope that it will be useful, but WITHOUT +# ANY WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS +# FOR A PARTICULAR PURPOSE. See the GNU General Public License for more +# details. + +# You should have received a copy of the GNU General Public License along with +# this program. If not, see + test.mkinmod.SFO <- function() { SFO.diffs <- c( @@ -5,7 +25,9 @@ test.mkinmod.SFO <- function() ) SFO.parms <- c("k_parent_sink") SFO.map <- list(parent = c(SFO = "parent")) - SFO <- list(diffs = SFO.diffs, parms = SFO.parms, map = SFO.map) + SFO.coefmat <- matrix("- k_parent_sink", dimnames = list("parent", "parent")) + SFO <- list(diffs = SFO.diffs, parms = SFO.parms, map = SFO.map, + coefmat = SFO.coefmat) class(SFO) <- "mkinmod" SFO.1 <- mkinmod( parent = list(type = "SFO", to = NULL, sink = TRUE) @@ -39,7 +61,13 @@ test.mkinmod.SFORB <- function() ) SFORB.parms <- c("k_parent_free_sink", "k_parent_free_bound", "k_parent_bound_free") SFORB.map <- list(parent = c(SFORB = "parent_free", SFORB = "parent_bound")) - SFORB <- list(diffs = SFORB.diffs, parms = SFORB.parms, map = SFORB.map) + vars <- paste("parent", c("free", "bound"), sep="_") + SFORB.coefmat <- matrix( + c("- k_parent_free_sink - k_parent_free_bound", "k_parent_bound_free", + "k_parent_free_bound", "- k_parent_bound_free"), nrow=2, byrow=TRUE, + dimnames=list(vars, vars)) + SFORB <- list(diffs = SFORB.diffs, parms = SFORB.parms, + map = SFORB.map, coefmat = SFORB.coefmat) class(SFORB) <- "mkinmod" SFORB.mkinmod <- mkinmod( parent = list(type = "SFORB", to = NULL, sink=TRUE) @@ -55,7 +83,12 @@ test.mkinmod.SFO_SFO <- function() ) SFO_SFO.parms <- c("k_parent_sink", "k_m1_sink", "k_parent_m1") SFO_SFO.map <- list(parent = c(SFO = "parent"), m1 = c(SFO = "m1")) - SFO_SFO <- list(diffs = SFO_SFO.diffs, parms = SFO_SFO.parms, map = SFO_SFO.map) + vars <- c("parent", "m1") + SFO_SFO.coefmat <- matrix(c("- k_parent_sink - k_parent_m1", + "0", "k_parent_m1", "- k_m1_sink"), nrow=2, byrow=TRUE, + dimnames=list(vars, vars)) + SFO_SFO <- list(diffs = SFO_SFO.diffs, parms = SFO_SFO.parms, + map = SFO_SFO.map, coefmat = SFO_SFO.coefmat) class(SFO_SFO) <- "mkinmod" SFO_SFO.mkinmod <- mkinmod( parent = list(type = "SFO", to = "m1", sink=TRUE), @@ -73,7 +106,14 @@ test.mkinmod.SFO_SFO2 <- function() ) SFO_SFO2.parms <- c("k_parent_sink", "k_m1_sink", "k_m2_sink", "k_parent_m1", "k_parent_m2") SFO_SFO2.map <- list(parent = c(SFO = "parent"), m1 = c(SFO = "m1"), m2 = c(SFO = "m2")) - SFO_SFO2 <- list(diffs = SFO_SFO2.diffs, parms = SFO_SFO2.parms, map = SFO_SFO2.map) + vars <- c("parent", "m1", "m2") + SFO_SFO2.coefmat <- matrix( + c("- k_parent_sink - k_parent_m1 - k_parent_m2", "0", "0", + "k_parent_m1", "- k_m1_sink", "0", + "k_parent_m2", "0", "- k_m2_sink"), nrow=3, byrow=TRUE, + dimnames=list(vars, vars)) + SFO_SFO2 <- list(diffs = SFO_SFO2.diffs, parms = SFO_SFO2.parms, + map = SFO_SFO2.map, coefmat = SFO_SFO2.coefmat) class(SFO_SFO2) <- "mkinmod" SFO_SFO2.mkinmod <- mkinmod( parent = list(type = "SFO", to = c("m1", "m2"), sink=TRUE), @@ -90,9 +130,16 @@ test.mkinmod.FOMC_SFO2 <- function() m1 = "d_m1 = - k_m1_sink * m1 + f_to_m1 * (alpha/beta) * ((time/beta) + 1)^-1 * parent", m2 = "d_m2 = - k_m2_sink * m2 + (1 - f_to_m1) * f_to_m2 * (alpha/beta) * ((time/beta) + 1)^-1 * parent" ) - FOMC_SFO2.parms <- c("alpha", "beta", "k_m1_sink", "k_m2_sink", "f_to_m1", "f_to_m2") - FOMC_SFO2.map <- list(parent = c(FOMC = "parent"), m1 = c(SFO = "m1"), m2 = c(SFO = "m2")) - FOMC_SFO2 <- list(diffs = FOMC_SFO2.diffs, parms = FOMC_SFO2.parms, map = FOMC_SFO2.map) + FOMC_SFO2.parms <- c("alpha", "beta", "k_m1_sink", "k_m2_sink", + "f_to_m1", "f_to_m2") + FOMC_SFO2.map <- list(parent = c(FOMC = "parent"), + m1 = c(SFO = "m1"), + m2 = c(SFO = "m2")) + FOMC_SFO2.ff <- c( + m1 = "f_to_m1", + m2 = "(1 - f_to_m1) * f_to_m2") + FOMC_SFO2 <- list(diffs = FOMC_SFO2.diffs, parms = FOMC_SFO2.parms, + map = FOMC_SFO2.map, ff = FOMC_SFO2.ff) class(FOMC_SFO2) <- "mkinmod" FOMC_SFO2.mkinmod <- mkinmod( parent = list(type = "FOMC", to = c("m1", "m2"), sink=TRUE), diff --git a/man/DFOP.solution.Rd b/man/DFOP.solution.Rd new file mode 100644 index 0000000..d30cf7f --- /dev/null +++ b/man/DFOP.solution.Rd @@ -0,0 +1,36 @@ +\name{DFOP.solution} +\Rdversion{1.1} +\alias{DFOP.solution} +\title{ +Dual First-Order in Parallel kinetics +} +\description{ + Function describing decline from a defined starting value using the sum + of two exponential decline functions. +} +\usage{ +DFOP.solution(t, parent.0, k1, k2, g) +} +\arguments{ + \item{t}{ Time. } + \item{parent.0}{ Starting value for the response variable at time zero. } + \item{k1}{ First kinetic constant. } + \item{k2}{ Second kinetic constant. } + \item{g}{ Fraction of the starting value declining according to the + first kinetic constant. + } +} +\value{ + The value of the response variable at time \code{t}. +} +\references{ + FOCUS (2006) \dQuote{Guidance Document on Estimating Persistence and + Degradation Kinetics from Environmental Fate Studies on Pesticides in EU + Registration} Report of the FOCUS Work Group on Degradation Kinetics, + EC Document Reference Sanco/10058/2005 version 2.0, 434 pp, + \url{http://focus.jrc.ec.europa.eu/dk} +} +\examples{ + \dontrun{plot(function(x) DFOP.solution(x, 100, 5, 0.5, 0.3), 0, 4, ylim=c(0,100))} +} +\keyword{ manip } diff --git a/man/FOCUS_2006_datasets.Rd b/man/FOCUS_2006_datasets.Rd index 04565f7..5053b88 100644 --- a/man/FOCUS_2006_datasets.Rd +++ b/man/FOCUS_2006_datasets.Rd @@ -11,7 +11,7 @@ Datasets A to F from the FOCUS Kinetics report from 2006 } \description{ -Data taken from an FOCUS (2006), p. 258. +Data taken from FOCUS (2006), p. 258. } \usage{FOCUS_2006_datasets} \format{ diff --git a/man/FOMC.solution.Rd b/man/FOMC.solution.Rd new file mode 100644 index 0000000..d04d34e --- /dev/null +++ b/man/FOMC.solution.Rd @@ -0,0 +1,49 @@ +\name{FOMC.solution} +\Rdversion{1.1} +\alias{FOMC.solution} +\title{ First-Order Multi-Compartment kinetics } +\description{ + Function describing exponential decline from a defined starting value, with + a decreasing rate constant. + + The form given here differs slightly from the original reference by Gustafson + and Holden (1990). The parameter \code{beta} corresponds to 1/beta in the + original equation. +} +\usage{ +FOMC.solution(t, parent.0, alpha, beta) +} +\arguments{ + \item{t}{ Time. } + \item{parent.0}{ Starting value for the response variable at time zero. } + \item{alpha}{ + Shape parameter determined by coefficient of variation of rate constant + values. } + \item{beta}{ + Location parameter. +} +} +\note{ + The solution of the FOMC kinetic model reduces to the + \code{\link{SFO.solution}} for large values of \code{alpha} and + \code{beta} with + \eqn{k = \frac{\beta}{\alpha}}{k = beta/alpha}. +} +\value{ + The value of the response variable at time \code{t}. +} +\references{ + FOCUS (2006) \dQuote{Guidance Document on Estimating Persistence and + Degradation Kinetics from Environmental Fate Studies on Pesticides in EU + Registration} Report of the FOCUS Work Group on Degradation Kinetics, + EC Document Reference Sanco/10058/2005 version 2.0, 434 pp, + \url{http://focus.jrc.ec.europa.eu/dk} + + Gustafson DI and Holden LR (1990) Nonlinear pesticide dissipation in soil: A + new model based on spatial variability. \emph{Environmental Science and + Technology} \bold{24}, 1032-1038 +} +\examples{ + \dontrun{plot(function(x) FOMC.solution(x, 100, 10, 2), 0, 2)} +} +\keyword{ manip } diff --git a/man/HS.solution.Rd b/man/HS.solution.Rd new file mode 100644 index 0000000..71f68a1 --- /dev/null +++ b/man/HS.solution.Rd @@ -0,0 +1,34 @@ +\name{HS.solution} +\Rdversion{1.1} +\alias{HS.solution} +\title{ Hockey-Stick kinetics } +\description{ + Function describing two exponential decline functions with a break point + between them. +} +\usage{ +HS.solution(t, parent.0, k1, k2, tb) +} +\arguments{ + \item{t}{ Time. } + \item{parent.0}{ Starting value for the response variable at time zero. } + \item{k1}{ First kinetic constant. } + \item{k2}{ Second kinetic constant. } + \item{tb}{ Break point. Before this time, exponential decline according + to \code{k1} is calculated, after this time, exponential decline proceeds + according to \code{k2}. } +} +\value{ + The value of the response variable at time \code{t}. +} +\references{ + FOCUS (2006) \dQuote{Guidance Document on Estimating Persistence and + Degradation Kinetics from Environmental Fate Studies on Pesticides in EU + Registration} Report of the FOCUS Work Group on Degradation Kinetics, + EC Document Reference Sanco/10058/2005 version 2.0, 434 pp, + \url{http://focus.jrc.ec.europa.eu/dk} +} +\examples{ + \dontrun{plot(function(x) HS.solution(x, 100, 2, 0.3, 0.5), 0, 2, ylim=c(0,100))} +} +\keyword{ manip } diff --git a/man/SFO.solution.Rd b/man/SFO.solution.Rd new file mode 100644 index 0000000..41a9ba9 --- /dev/null +++ b/man/SFO.solution.Rd @@ -0,0 +1,29 @@ +\name{SFO.solution} +\Rdversion{1.1} +\alias{SFO.solution} +\title{ Single First-Order kinetics } +\description{ + Function describing exponential decline from a defined starting value. +} +\usage{ + SFO.solution(t, parent.0, k) +} +\arguments{ + \item{t}{ Time. } + \item{parent.0}{ Starting value for the response variable at time zero. } + \item{k}{ Kinetic constant. } +} +\value{ + The value of the response variable at time \code{t}. +} +\references{ + FOCUS (2006) \dQuote{Guidance Document on Estimating Persistence and + Degradation Kinetics from Environmental Fate Studies on Pesticides in EU + Registration} Report of the FOCUS Work Group on Degradation Kinetics, + EC Document Reference Sanco/10058/2005 version 2.0, 434 pp, + \url{http://focus.jrc.ec.europa.eu/dk} +} +\examples{ + \dontrun{plot(function(x) SFO.solution(x, 100, 3), 0, 2)} +} +\keyword{ manip } diff --git a/man/SFORB.solution.Rd b/man/SFORB.solution.Rd new file mode 100644 index 0000000..a935f69 --- /dev/null +++ b/man/SFORB.solution.Rd @@ -0,0 +1,36 @@ +\name{SFORB.solution} +\Rdversion{1.1} +\alias{SFORB.solution} +\title{ Single First-Order Reversible Binding kinetics } +\description{ + Function describing the solution of the differential equations describing + the kinetic model with first-order terms for a two-way transfer from a free + to a bound fraction, and a first-order degradation term for the free + fraction. The initial condition is a defined amount in the free fraction and + no substance in the bound fraction. +} +\usage{ + SFORB.solution(t, parent.0, k_12, k_21, k_1output) +} +\arguments{ + \item{t}{ Time. } + \item{parent.0}{ Starting value for the response variable at time zero. } + \item{k_12}{ Kinetic constant describing transfer from free to bound. } + \item{k_21}{ Kinetic constant describing transfer from bound to free. } + \item{k_1output}{ Kinetic constant describing degradation of the free fraction. } +} +\value{ + The value of the response variable, which is the sum of free and bound + fractions at time \code{t}. +} +\references{ + FOCUS (2006) \dQuote{Guidance Document on Estimating Persistence and + Degradation Kinetics from Environmental Fate Studies on Pesticides in EU + Registration} Report of the FOCUS Work Group on Degradation Kinetics, + EC Document Reference Sanco/10058/2005 version 2.0, 434 pp, + \url{http://focus.jrc.ec.europa.eu/dk} +} +\examples{ + \dontrun{plot(function(x) SFORB.solution(x, 100, 0.5, 2, 3), 0, 2)} +} +\keyword{ manip } diff --git a/man/mkin_long_to_wide.Rd b/man/mkin_long_to_wide.Rd index 97791e6..6fa1860 100644 --- a/man/mkin_long_to_wide.Rd +++ b/man/mkin_long_to_wide.Rd @@ -4,7 +4,7 @@ Convert a dataframe from long to wide format. } \usage{ -mkin_long_to_wide(long_data, time = "time") +mkin_long_to_wide(long_data, time = "time", outtime = "time") } \description{ This function takes a dataframe in the long form as required by \code{\link{modCost}} @@ -17,7 +17,10 @@ mkin_long_to_wide(long_data, time = "time") \code{time} argument and one column of observed values named "value". } \item{time}{ - The name of the time variable. + The name of the time variable in the long input data. +} + \item{outtime}{ + The name of the time variable in the wide output data. } } \value{ diff --git a/man/mkinerrmin.Rd b/man/mkinerrmin.Rd index 4bbf96a..654115b 100644 --- a/man/mkinerrmin.Rd +++ b/man/mkinerrmin.Rd @@ -42,5 +42,4 @@ mkinerrmin(errdata, n.parms, alpha = 0.05) EC Document Reference Sanco/10058/2005 version 2.0, 434 pp, \url{http://focus.jrc.ec.europa.eu/dk} } -\author{ Johannes Ranke } \keyword{ manip } diff --git a/man/mkinfit.Rd b/man/mkinfit.Rd index 0ec2d21..d4139eb 100644 --- a/man/mkinfit.Rd +++ b/man/mkinfit.Rd @@ -15,7 +15,10 @@ mkinfit(mkinmod, observed, state.ini = c(100, rep(0, length(mkinmod$diffs) - 1)), lower = 0, upper = Inf, fixed_parms = NULL, fixed_initials = names(mkinmod$diffs)[-1], - plot = FALSE, quiet = FALSE, err = NULL, weight = "none", scaleVar = FALSE, ...) + eigen = FALSE, + plot = FALSE, quiet = FALSE, err = NULL, weight = "none", + scaleVar = FALSE, + atol = 1e-6, ...) } \arguments{ \item{mkinmod}{ @@ -32,8 +35,11 @@ mkinfit(mkinmod, observed, \code{\link{modFit}}. } \item{parms.ini}{ - A named vector if initial values for the parameters, including both parameters to + A named vector if initial values for the parameters, including parameters to be optimised and potentially also fixed parameters as indicated by \code{fixed_parms}. + The default is to set the initial values to 0.1. The setting of the initial values for + the parameters has a strong impart on performance and it lies in the responsibilty of the + user to set sensible initial values. } \item{state.ini}{ A named vector of initial values for the state variables of the model. In case the @@ -47,9 +53,10 @@ mkinfit(mkinmod, observed, negative values to not make sense for the models currently created by \code{\link{mkinmod}}. } \item{upper}{ - Upper bounds for the parameters, passed to \code{\link{modFit}}. Defaults to \code{Inf}. Setting - non-infinite upper bounds has a strong impact on performance, and using a method like "L-BFGS-B" (by - specifying an additional \code{method} argument) is recommended. + Upper bounds for the parameters, passed to \code{\link{modFit}}. Defaults to \code{Inf} + except for formation fraction parameters. Setting non-infinite upper bounds has a strong + impact on performance, and using a method like "L-BFGS-B" (by specifying an additional + \code{method} argument) is recommended. } \item{fixed_parms}{ The names of parameters that should not be optimised but rather kept at the values @@ -59,6 +66,12 @@ mkinfit(mkinmod, observed, The names of model variables for which the initial state at time 0 should be excluded from the optimisation. Defaults to all state variables except for the first one. } + \item{eigen}{ + Should the solution of the system of differential equations be based on the + spectral decomposition of the coefficient matrix in cases that this is + possible? Be aware that the results may differ from the results returned using + the ode solver. + } \item{plot}{ Should the observed values and the numerical solutions be plotted at each stage of the optimisation? @@ -77,13 +90,17 @@ mkinfit(mkinmod, observed, Will be passed to \code{\link{modCost}}. Default is not to scale Variables according to the number of observations. } + \item{atol}{ + Absolute error tolerance, passed to \code{\link{ode}}. Default is 1e-6 as in + \code{\link{lsoda}}. + } \item{\dots}{ Further arguments that will be passed to \code{\link{modFit}}. } } \value{ - A list with "mkinfit" and "modFit" in the class attribute. Thus, at - present, a summary can be obtained by \code{\link{summary.modFit}}. + A list with "mkinfit" and "modFit" in the class attribute. + A summary can be obtained by \code{\link{summary.mkinfit}}. } \author{ Johannes Ranke diff --git a/man/mkinmod.Rd b/man/mkinmod.Rd index 7ec9627..7c11735 100644 --- a/man/mkinmod.Rd +++ b/man/mkinmod.Rd @@ -15,13 +15,16 @@ mkinmod(...) \item{...}{ For each observed variable, a list has to be specified as an argument, containing at least a component \code{type}, specifying the type of kinetics to use - for the variable. Currently, only single first order kinetics "SFO" or - single first order with reversible binding "SFORB" are implemented, as well as - "FOMC" for the first compartment which is assumed to be the source compartment. - Optional components of each argument are \code{to}, a vector of names of - variables to which a transfer is to be assumed in the model, and - \code{sink}, a logical specifying if transformation to unspecified - compounds (sink) is to be assumed in the model (defaults to \code{TRUE}) + for the variable. Currently, single first order kinetics "SFO" or + single first order with reversible binding "SFORB" are implemented for all + variables, while + "FOMC", "DFOP" and "HS" can additionally be chosen for the first + variable which is assumed to be the source compartment. Optional components + of each argument are \code{to}, a + vector of names of variables to which a transfer is to be assumed in the + model, and \code{sink}, a logical specifying if transformation to + unspecified compounds (sink) is to be assumed in the model (defaults to + \code{TRUE}) } } \value{ @@ -31,6 +34,7 @@ mkinmod(...) \item{parms}{ A vector of parameter names occurring in the differential equations. } \item{map}{ A list containing named character vectors for each observed variable, specifying the modelling variables by which it is represented. } + \item{coefmat}{ The coefficient matrix, if the system of differential equations can be represented by one. } } \author{ Johannes Ranke diff --git a/man/mkinplot.Rd b/man/mkinplot.Rd index 58959d7..b72675a 100644 --- a/man/mkinplot.Rd +++ b/man/mkinplot.Rd @@ -10,7 +10,8 @@ } \usage{ mkinplot(fit, xlab = "Time", ylab = "Observed", - xlim = range(fit$data$time), ylim = range(fit$data$observed, na.rm=TRUE), ...) + xlim = range(fit$data$time), ylim = range(fit$data$observed, na.rm=TRUE), + legend = TRUE, ...) } \arguments{ \item{fit}{ @@ -28,6 +29,9 @@ \item{ylim}{ plot range in y direction. } + \item{legend}{ + legend specifying if a legend should be included in the plot. + } \item{\dots}{ further arguments passed to \code{\link{plot}}. } diff --git a/man/mkinresplot.Rd b/man/mkinresplot.Rd new file mode 100644 index 0000000..0b48692 --- /dev/null +++ b/man/mkinresplot.Rd @@ -0,0 +1,64 @@ +\name{mkinresplot} +\alias{mkinresplot} +\title{ + Function to plot residuals stored in an mkin object +} +\description{ + This function plots the residuals for the specified subset of the + observed variables from an mkinfit object. +} +\usage{ + mkinresplot(object, obs_vars = vector(), + xlab = "Time [days]", ylab = "Residual [\% of applied radioactivity]", + maxabs = "auto", legend = TRUE, lpos = "topright", ...) +} +\arguments{ + \item{object}{ + A fit represented in an \code{\link{mkinfit}} object. +} + \item{obs_vars}{ + A character vector of names of the observed variables for which residuals + should be plotted. +} + \item{xlab}{ + Label for the x axis. Defaults to "Time [days]". +} + \item{ylab}{ + Label for the y axis. Defaults to "Residual [\% of applied radioactivity]". +} + \item{maxabs}{ + Maximum absolute value of the residuals. This is used for the scaling of + the y axis and defaults to "auto". +} + \item{legend}{ + Should a legend be plotted? Defaults to "TRUE". +} + \item{lpos}{ + Where should the legend be placed? Default is "topright". Will be passed on to + \code{\link{legend}}. } + \item{\dots}{ + further arguments passed to \code{\link{plot}}. +} +} +\value{ + Nothing is returned by this function, as it is called for its side effect, namely to produce a plot. +} +\author{ + Katrin Lindenberger and Johannes Ranke +} + +\seealso{ + \code{\link{mkinplot}}, for a way to plot the data and the fitted lines of the + mkinfit object. } +\examples{ +data <- mkin_wide_to_long(schaefer07_complex_case, time = "time") +model <- mkinmod( + parent = list(type = "SFO", to = c("A1", "B1", "C1"), sink = FALSE), + A1 = list(type = "SFO", to = "A2"), + B1 = list(type = "SFO"), + C1 = list(type = "SFO"), + A2 = list(type = "SFO")) +\dontrun{fit <- mkinfit(model, data, plot=TRUE)} +\dontrun{mkinresplot(fit, "A1")} +} +\keyword{ hplot } diff --git a/man/mkinstart.Rd b/man/mkinstart.Rd new file mode 100644 index 0000000..ec1204f --- /dev/null +++ b/man/mkinstart.Rd @@ -0,0 +1,38 @@ +\name{mkinstart} +\alias{mkinstart} +\title{ + Generate starting parameters for optimisations +} +\description{ + This function is supposed to analyse a kinetic model and kinetic data in + order to generate suitable starting parameters for fitting the model. + It does not do anything really useful at the moment. +} +\usage{ +mkinstart(model, data, mode = "auto") +} +\arguments{ + \item{model}{ + A kinetic model of class \code{\link{mkinmod}}. +} + \item{data}{ + Kinetic data in wide format suitable for fitting with \code{\link{mkinfit}}. +} + \item{mode}{ + How the starting parameters should be generated. At the moment, only + "auto" is supported, which internally uses \code{\link{kinfit}}. +} +} +\details{ +%% ~~ If necessary, more details than the description above ~~ +} +\value{ + A named vector of starting parameters. +} +\author{ + Johannes Ranke +} +\examples{ + +} +\keyword{ manip } diff --git a/man/summary.mkinfit.Rd b/man/summary.mkinfit.Rd index 1c30589..8a8c6ab 100644 --- a/man/summary.mkinfit.Rd +++ b/man/summary.mkinfit.Rd @@ -11,8 +11,8 @@ and residual values. } \usage{ -\method{summary}{mkinfit}(object, data = TRUE, distimes = TRUE, cov = FALSE, ...) -\method{print}{summary.mkinfit}(x, digits = max(3, getOption("digits") - 3), ...) +\method{summary}{mkinfit}(object, data = TRUE, distimes = TRUE, ff = TRUE, cov = FALSE, ...) +\method{print}{summary.mkinfit}(x, digits = max(3, getOption("digits") - 3), tval = TRUE, ...) } \arguments{ @@ -26,13 +26,20 @@ logical, indicating whether the data should be included in the summary. } \item{distimes}{ - logical, indicating whether DT50 and DT90 values shoule be included. + logical, indicating whether DT50 and DT90 values should be included. +} + \item{ff}{ + logical, indicating whether formation fractions should be included. } \item{cov}{ logical, indicating whether parameter covariances should be calculated. Passed to \code{\link{summary.modFit}}. } \item{digits}{ Number of digits to use for printing +} + \item{tval}{ + Should the test statistic of the t-test for parameter significance be + printed? Defaults to \code{TRUE}. Saves vertical space if set to \code{FALSE}. } \item{\dots}{ optional arguments passed to methods like \code{print}. @@ -47,6 +54,7 @@ Passed to \code{\link{summary.modFit}}. } \item{fixed }{The values of fixed parameters.} \item{errmin }{The chi2 error levels for each observed variable.} \item{disstimes }{The DT50 and DT90 values for each observed variable.} + \item{ff }{The estimated formation fractions derived from the fitted model.} The print method is called for its side effect, i.e. printing the summary. } \references{ @@ -57,7 +65,7 @@ Passed to \code{\link{summary.modFit}}. } \url{http://focus.jrc.ec.europa.eu/dk} } \author{ - Johannes Ranke + Johannes Ranke } \examples{ summary(mkinfit(mkinmod(parent = list(type = "SFO")), FOCUS_2006_A)) diff --git a/tests/doRUnit.R b/tests/doRUnit.R index e2ad4cd..ed3ef1d 100644 --- a/tests/doRUnit.R +++ b/tests/doRUnit.R @@ -1,17 +1,10 @@ +# $Id: doRUnit.R 96 2011-04-29 11:10:40Z jranke $ +# Adapted from a version around 2.9 of the rcdk package by Rajarshi Guha if(require("RUnit", quietly=TRUE)) { - ## --- Setup --- - - pkg <- "mkin" # <-- Change to package name! - if(Sys.getenv("RCMDCHECK") == "FALSE") { - ## Path to unit tests for standalone running under Makefile (not R CMD check) - ## PKG/tests/../inst/unitTests - path <- file.path(getwd(), "..", "inst", "unitTests") - } else { - ## Path to unit tests for R CMD check - ## PKG.Rcheck/tests/../PKG/unitTests - path <- system.file(package=pkg, "unitTests") - } + pkg <- "mkin" + path <- system.file(package=pkg, "unitTests") + cat("\nRunning unit tests\n") print(list(pkg=pkg, getwd=getwd(), pathToUnitTests=path)) -- cgit v1.2.1