From c1144753adfa0809003085009ebd85f8af9beda8 Mon Sep 17 00:00:00 2001 From: jranke Date: Tue, 10 Apr 2012 21:50:22 +0000 Subject: - Fitting and summaries now work with the new parameter transformations. - The SFORB models with metabolites is broken (see TODO) - Moved the vignette to the location recommended since R 2.14 - Added the missing documentation - Commented out the schaefer_complex_case test, as this version of mkin is not able to fit a model without sink and therefore mkin estimated parameters are quite different git-svn-id: svn+ssh://svn.r-forge.r-project.org/svnroot/kinfit/pkg/mkin@22 edb9625f-4e0d-4859-8d74-9fd3b1da38cb --- inst/doc/Rplots.pdf | 23902 ---------------------------------------------- inst/doc/header.tex | 31 - inst/doc/mkin.Rnw | 162 - inst/doc/mkin.pdf | Bin 178902 -> 0 bytes inst/doc/references.bib | 62 - inst/doc/run.bat | 5 - 6 files changed, 24162 deletions(-) delete mode 100644 inst/doc/Rplots.pdf delete mode 100644 inst/doc/header.tex delete mode 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-\newcommand{\Rpackage}[1]{{\normalfont\fontseries{b}\selectfont #1}} -\newcommand{\Robject}[1]{\texttt{#1}} -\newcommand{\Rclass}[1]{\textit{#1}} -\newcommand{\Rcmd}[1]{\texttt{#1}} - -\newcommand{\RR}{\textsf{R}} - -\RequirePackage[T1]{fontenc} -\RequirePackage{graphicx,ae,fancyvrb} -\IfFileExists{upquote.sty}{\RequirePackage{upquote}}{} -\usepackage{relsize} - -\DefineVerbatimEnvironment{Sinput}{Verbatim}{baselinestretch=1.05} -\DefineVerbatimEnvironment{Soutput}{Verbatim}{fontfamily=courier, - baselinestretch=1.05, - fontshape=it, - fontsize=\relsize{-1}} -\DefineVerbatimEnvironment{Scode}{Verbatim}{} -\newenvironment{Schunk}{}{} diff --git a/inst/doc/mkin.Rnw b/inst/doc/mkin.Rnw deleted file mode 100644 index 2f71151a..00000000 --- a/inst/doc/mkin.Rnw +++ /dev/null @@ -1,162 +0,0 @@ -% $Id: mkin.Rnw 66 2010-09-03 08:50:26Z jranke $ -%%\VignetteIndexEntry{Routines for fitting kinetic models with one or more state variables to chemical degradation data} -%%VignetteDepends{FME} -%%\usepackage{Sweave} -\documentclass[12pt,a4paper]{article} -\usepackage{a4wide} -%%\usepackage[lists,heads]{endfloat} -\input{header} -\hypersetup{ - pdftitle = {mkin - Routines for fitting kinetic models with one or more state variables to chemical degradation data}, - pdfsubject = {Manuscript}, - pdfauthor = {Johannes Ranke}, - colorlinks = {true}, - linkcolor = {blue}, - citecolor = {blue}, - urlcolor = {red}, - hyperindex = {true}, - linktocpage = {true}, -} -\SweaveOpts{engine=R, eps=FALSE, keep.source = TRUE} -<>= -options(prompt = "R> ") -options(SweaveHooks = list( - cex = function() par(cex.lab = 1.3, cex.axis = 1.3))) -@ -\begin{document} -\title{mkin -\\ -Routines for fitting kinetic models with one or more state variables to chemical degradation data} -\author{\textbf{Johannes Ranke} \\ -%EndAName -Product Safety \\ -Harlan Laboratories Ltd. \\ -Zelgliweg 1, CH--4452 Itingen, Switzerland} -\maketitle - -\begin{abstract} -In the regulatory evaluation of chemical substances like plant protection -products (pesticides), biocides and other chemicals, degradation data play an -important role. For the evaluation of pesticide degradation experiments, -detailed guidance has been developed, based on nonlinear optimisation. -The \RR{} add-on package \Rpackage{mkin} implements fitting some of the models -recommended in this guidance from within R and calculates some statistical -measures for data series within one or more compartments, for parent and -metabolites. -\end{abstract} - - -\thispagestyle{empty} \setcounter{page}{0} - -\clearpage - -\tableofcontents - -\textbf{Key words}: Kinetics, FOCUS, nonlinear optimisation - -\section{Introduction} -\label{intro} - -Many approaches are possible regarding the evaluation of chemical degradation -data. The \Rpackage{kinfit} package \citep{pkg:kinfit} in \RR{} -\citep{rcore2010} implements the approach recommended in the kinetics report -provided by the FOrum for Co-ordination of pesticide fate models and their -USe \citep{FOCUS2006} for simple data series for one parent compound in one -compartment. - -The \Rpackage{mkin} package \citep{pkg:mkin} extends this approach to data series -with metabolites and more than one compartment and includes the possibility -for back reactions. - -\section{Example} -\label{exam} - -In the following, requirements for data formatting are explained. Then the -procedure for fitting the four kinetic models recommended by the FOCUS group -to an example dataset for parent only given in the FOCUS kinetics report is -illustrated. The explanations are kept rather verbose in order to lower the -barrier for \RR{} newcomers. - -\subsection{Data format} - -The following listing shows example dataset C from the FOCUS kinetics -report as distributed with the \Rpackage{mkin} package - -<>= -library("mkin") -FOCUS_2006_C -@ - -Note that the data needs to be in the format of a data frame containing a -variable \Robject{name} specifying the observed variable, indicating the -compound name and, if applicable, the compartment, a variable \Robject{time} -containing sampling times, and a numeric variable \Robject{value} specifying -the observed value of the variable. If a further variable \Robject{error} -is present, this will be used to give different weights to the data points -(the higher the error, the lower the weight, see the help page of the -\Robject{modCost} function of the \Rpackage{FME} package \citep{soetaert10}). -Replicate measurements are not recorded in extra columns but simply appended, -leading to multiple occurrences of the sampling times \Robject{time}. - -Small to medium size dataset can be conveniently entered directly as \RR{} code -as shown in the following listing - -<>= -example_data <- data.frame( - name = rep("parent", 9), - time = c(0, 1, 3, 7, 14, 28, 63, 91, 119), - value = c(85.1, 57.9, 29.9, 14.6, 9.7, 6.6, 4, 3.9, 0.6) -) -@ - -\subsection{Model definition} - -The next task is to define the model to be fitted to the data. In order to -facilitate this task, a convenience function \Robject{mkinmod} is available. - -<>= -SFO <- mkinmod(parent = list(type = "SFO")) -SFORB <- mkinmod(parent = list(type = "SFORB")) -SFO_SFO <- mkinmod( - parent = list(type = "SFO", to = "m1", sink = TRUE), - m1 = list(type = "SFO")) -SFORB_SFO <- mkinmod( - parent = list(type = "SFORB", to = "m1", sink = TRUE), - m1 = list(type = "SFO")) -@ - -The model definitions given above define sets of linear first-order ordinary -differential equations. In these cases, a coefficient matrix is also returned. - -Other models that include time on the right-hand side of the differential -equation are the first-order multi-compartment (FOMC) model and the -Hockey-Stick (HS) model. At present, only the FOMC model can only be used, and -only for the parent compound. - -\subsection{Fitting the model} - -Then the model parameters should be fitted to the data. The function -\Robject{mkinfit} internally creates a cost function using \Robject{modCost} -from the \Rpackage{FME} package and the produces a fit using \Robject{modFit} -from the same package. In cases of linear first-order differential -equations, the solution used for calculating the cost function is based -on the fundamental system of the coefficient matrix, as proposed by -\citet{bates88}. - -<>= -# Do not show significance stars as they interfere with vignette generation -options(show.signif.stars = FALSE) -SFO.fit <- mkinfit(SFO, FOCUS_2006_C) -summary(SFO.fit) -SFORB.fit <- mkinfit(SFORB, FOCUS_2006_C) -summary(SFORB.fit) -SFO_SFO.fit <- mkinfit(SFO_SFO, FOCUS_2006_D, plot=TRUE) -summary(SFO_SFO.fit, data=FALSE) -SFORB_SFO.fit <- mkinfit(SFORB_SFO, FOCUS_2006_D, plot=TRUE) -summary(SFORB_SFO.fit, data=FALSE) -@ - -\bibliographystyle{plainnat} -\bibliography{references} - -\end{document} -% vim: set foldmethod=syntax: diff --git a/inst/doc/mkin.pdf b/inst/doc/mkin.pdf deleted file mode 100644 index f963d1e6..00000000 Binary files a/inst/doc/mkin.pdf and /dev/null differ diff --git a/inst/doc/references.bib b/inst/doc/references.bib deleted file mode 100644 index 24672e2e..00000000 --- a/inst/doc/references.bib +++ /dev/null @@ -1,62 +0,0 @@ -@Manual{pkg:kinfit, - title = {kinfit: {R}outines for fitting simple kinetic models to chemical degradation data}, - author = {Johannes Ranke}, - year = {2010}, - url = {http://CRAN.R-project.org} -} - -@Manual{pkg:mkin, - title = {mkin: {R}outines for fitting kinetic models with one or more state variables to chemical degradation data}, - author = {Johannes Ranke}, - year = {2010}, - url = {http://CRAN.R-project.org} -} - -@Article{soetaert10, - title = {Inverse Modelling, Sensitivity and Monte Carlo Analysis in {R} Using Package {FME}}, - author = {Karline Soetaert and Thomas Petzoldt}, - journal = {Journal of Statistical Software}, - year = {2010}, - volume = {33}, - number = {3}, - pages = {1--28}, - url = {http://www.jstatsoft.org/v33/i03/} -} - -@Manual{ rcore2010, - title = {\textsf{R}: A Language and Environment for Statistical - Computing}, - author = {{R Development Core Team}}, - organization = {R Foundation for Statistical Computing}, - address = {Vienna, Austria}, - year = 2010, - note = {{ISBN} 3-900051-07-0}, - url = {http://www.R-project.org} -} - -@Manual{ FOCUS2006, - title = {Guidance Document on Estimating Persistence and - Degradation Kinetics from Environmental Fate Studies on Pesticides in EU - Registration. Report of the FOCUS Work Group on Degradation Kinetics}, - note = {EC Document Reference Sanco/10058/2005 version 2.0}, - author = {{FOCUS Work Group on Degradation Kinetics}}, - year = {2006}, - url = {http://focus.jrc.ec.europa.eu/dk} -} - -@Inproceedings{ schaefer2007, - title = {{KinGUI}: a new kinetic software tool for evaluations according to FOCUS degradation kinetics}, - author = {D. Sch\"{a}fer and M. Mikolasch and P. Rainbird and B. Harvey}, - booktitle = {Proceedings of the XIII Symposium Pesticide Chemistry}, - editor = {Del Re A. A. M. and Capri E. and Fragoulis G. and Trevisan M.}, - year = {2007}, - address = {Piacenza}, - pages = {916--923} -} - -@Book{ bates88, - title = {Nonlinear regression and its applications}, - author = {D. Bates and D. Watts}, - year = {1988}, - publisher = {Wiley-Interscience} -} diff --git a/inst/doc/run.bat b/inst/doc/run.bat deleted file mode 100644 index c28c6663..00000000 --- a/inst/doc/run.bat +++ /dev/null @@ -1,5 +0,0 @@ -R.exe -e "Sweave('mkin.Rnw', stylepath=FALSE)" -pdflatex.exe mkin -bibtex.exe mkin -pdflatex.exe mkin -pdflatex.exe mkin -- cgit v1.2.1