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diff --git a/man/linearity.Rd b/man/linearity.Rd new file mode 100644 index 0000000..52c2423 --- /dev/null +++ b/man/linearity.Rd @@ -0,0 +1,64 @@ +% Generated by roxygen2: do not edit by hand +% Please edit documentation in R/linearity.R +\name{linearity} +\alias{linearity} +\title{Assess the linearity of a calibration curve} +\usage{ +linearity(x, y, method = c("slope", "curvature"), tolerance = 0.1) +} +\arguments{ +\item{x}{numeric vector of independent values (usually concentrations).} + +\item{y}{numeric vector of dependent values (usually the signal of the +analytical device).} + +\item{method}{character string. Supported methods are "slope" and +"curvature".} + +\item{tolerance}{numeric value between 0 and 1, describing the acceptable +deviation from the median of the slopes or the signal-to-concentration +ratio. The default tolerance is 10\%.} +} +\value{ +returns a diagnostic plot +} +\description{ +A function to create diagnostic plots for the assessment of the linearity of +calibration data based on their point-to-point slope or the curvature. +The underlying methods follow ISO 84 66-1:2021 and DIN 32 402-51:2017 +(German Industrial Norm). +} +\details{ +The point-to-point slope method is based on the assumption that the slope +between two points should not vary greatly within the linear range. + +The curvature method is similar to the point-to-point slope method. Here, +the ratio between the instrument signal and the concentration of the +calibration standard is assumed not to vary greatly within the linear range. + +The use of the Mandel test is discouraged due to its limitations in the +identification of non-linear behaviour of calibration curves (Andrade and +Gomes-Carracedo, 2013). +} +\examples{ +# Continuous Flow Analysis (CFA) data +data(din38402b1) + +# Point-to-point slope plot +linearity(din38402b1$conc, din38402b1$ext, method = "slope") + +# Curvature plot +linearity(din38402b1$conc, din38402b1$ext, method = "curvature") + +} +\references{ +ISO 8466-1:2021. Water quality — Calibration and evaluation of +analytical methods — Part 1: Linear calibration function + +J. M. Andrade and M. P. Gomez-Carracedo (2013) Notes on the use of +Mandel's test to check for nonlinearity in laboratory calibrations. +Analytical Methods 5(5), 1145 - 1149. +} +\author{ +Anıl Axel Tellbüscher +} |