diff options
author | jranke <jranke@edb9625f-4e0d-4859-8d74-9fd3b1da38cb> | 2012-04-10 21:50:22 +0000 |
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committer | jranke <jranke@edb9625f-4e0d-4859-8d74-9fd3b1da38cb> | 2012-04-10 21:50:22 +0000 |
commit | c1144753adfa0809003085009ebd85f8af9beda8 (patch) | |
tree | c07afafb9e6a3ffd1248167f4e40983bb3ef85fc /inst/doc | |
parent | d3df16102c5ed4bf9182b4f1893561e99eaed166 (diff) |
- Fitting and summaries now work with the new parameter transformations.
- The SFORB models with metabolites is broken (see TODO)
- Moved the vignette to the location recommended since R 2.14
- Added the missing documentation
- Commented out the schaefer_complex_case test, as this version of
mkin is not able to fit a model without sink and therefore
mkin estimated parameters are quite different
git-svn-id: svn+ssh://svn.r-forge.r-project.org/svnroot/kinfit/pkg/mkin@22 edb9625f-4e0d-4859-8d74-9fd3b1da38cb
Diffstat (limited to 'inst/doc')
-rw-r--r-- | inst/doc/Rplots.pdf | 23902 | ||||
-rw-r--r-- | inst/doc/header.tex | 31 | ||||
-rw-r--r-- | inst/doc/mkin.Rnw | 162 | ||||
-rw-r--r-- | inst/doc/mkin.pdf | bin | 178902 -> 0 bytes | |||
-rw-r--r-- | inst/doc/references.bib | 62 | ||||
-rw-r--r-- | inst/doc/run.bat | 5 |
6 files changed, 0 insertions, 24162 deletions
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-\usepackage{amsfonts}
-\usepackage{latexsym}
-\usepackage{amsmath}
-\usepackage{amssymb}
-\usepackage{graphicx}
-\usepackage{parskip}
-\usepackage[round]{natbib}
-\usepackage{amstext}
-\usepackage{hyperref}
-\usepackage[latin1]{inputenc}
-
-\newcommand{\Rpackage}[1]{{\normalfont\fontseries{b}\selectfont #1}}
-\newcommand{\Robject}[1]{\texttt{#1}}
-\newcommand{\Rclass}[1]{\textit{#1}}
-\newcommand{\Rcmd}[1]{\texttt{#1}}
-
-\newcommand{\RR}{\textsf{R}}
-
-\RequirePackage[T1]{fontenc}
-\RequirePackage{graphicx,ae,fancyvrb}
-\IfFileExists{upquote.sty}{\RequirePackage{upquote}}{}
-\usepackage{relsize}
-
-\DefineVerbatimEnvironment{Sinput}{Verbatim}{baselinestretch=1.05}
-\DefineVerbatimEnvironment{Soutput}{Verbatim}{fontfamily=courier,
- baselinestretch=1.05,
- fontshape=it,
- fontsize=\relsize{-1}}
-\DefineVerbatimEnvironment{Scode}{Verbatim}{}
-\newenvironment{Schunk}{}{}
diff --git a/inst/doc/mkin.Rnw b/inst/doc/mkin.Rnw deleted file mode 100644 index 2f71151a..00000000 --- a/inst/doc/mkin.Rnw +++ /dev/null @@ -1,162 +0,0 @@ -% $Id: mkin.Rnw 66 2010-09-03 08:50:26Z jranke $
-%%\VignetteIndexEntry{Routines for fitting kinetic models with one or more state variables to chemical degradation data}
-%%VignetteDepends{FME}
-%%\usepackage{Sweave}
-\documentclass[12pt,a4paper]{article}
-\usepackage{a4wide}
-%%\usepackage[lists,heads]{endfloat}
-\input{header}
-\hypersetup{
- pdftitle = {mkin - Routines for fitting kinetic models with one or more state variables to chemical degradation data},
- pdfsubject = {Manuscript},
- pdfauthor = {Johannes Ranke},
- colorlinks = {true},
- linkcolor = {blue},
- citecolor = {blue},
- urlcolor = {red},
- hyperindex = {true},
- linktocpage = {true},
-}
-\SweaveOpts{engine=R, eps=FALSE, keep.source = TRUE}
-<<setup, echo = FALSE, results = hide>>=
-options(prompt = "R> ")
-options(SweaveHooks = list(
- cex = function() par(cex.lab = 1.3, cex.axis = 1.3)))
-@
-\begin{document}
-\title{mkin -\\
-Routines for fitting kinetic models with one or more state variables to chemical degradation data}
-\author{\textbf{Johannes Ranke} \\
-%EndAName
-Product Safety \\
-Harlan Laboratories Ltd. \\
-Zelgliweg 1, CH--4452 Itingen, Switzerland}
-\maketitle
-
-\begin{abstract}
-In the regulatory evaluation of chemical substances like plant protection
-products (pesticides), biocides and other chemicals, degradation data play an
-important role. For the evaluation of pesticide degradation experiments,
-detailed guidance has been developed, based on nonlinear optimisation.
-The \RR{} add-on package \Rpackage{mkin} implements fitting some of the models
-recommended in this guidance from within R and calculates some statistical
-measures for data series within one or more compartments, for parent and
-metabolites.
-\end{abstract}
-
-
-\thispagestyle{empty} \setcounter{page}{0}
-
-\clearpage
-
-\tableofcontents
-
-\textbf{Key words}: Kinetics, FOCUS, nonlinear optimisation
-
-\section{Introduction}
-\label{intro}
-
-Many approaches are possible regarding the evaluation of chemical degradation
-data. The \Rpackage{kinfit} package \citep{pkg:kinfit} in \RR{}
-\citep{rcore2010} implements the approach recommended in the kinetics report
-provided by the FOrum for Co-ordination of pesticide fate models and their
-USe \citep{FOCUS2006} for simple data series for one parent compound in one
-compartment.
-
-The \Rpackage{mkin} package \citep{pkg:mkin} extends this approach to data series
-with metabolites and more than one compartment and includes the possibility
-for back reactions.
-
-\section{Example}
-\label{exam}
-
-In the following, requirements for data formatting are explained. Then the
-procedure for fitting the four kinetic models recommended by the FOCUS group
-to an example dataset for parent only given in the FOCUS kinetics report is
-illustrated. The explanations are kept rather verbose in order to lower the
-barrier for \RR{} newcomers.
-
-\subsection{Data format}
-
-The following listing shows example dataset C from the FOCUS kinetics
-report as distributed with the \Rpackage{mkin} package
-
-<<FOCUS_2006_C_data, echo=TRUE, eval=TRUE>>=
-library("mkin")
-FOCUS_2006_C
-@
-
-Note that the data needs to be in the format of a data frame containing a
-variable \Robject{name} specifying the observed variable, indicating the
-compound name and, if applicable, the compartment, a variable \Robject{time}
-containing sampling times, and a numeric variable \Robject{value} specifying
-the observed value of the variable. If a further variable \Robject{error}
-is present, this will be used to give different weights to the data points
-(the higher the error, the lower the weight, see the help page of the
-\Robject{modCost} function of the \Rpackage{FME} package \citep{soetaert10}).
-Replicate measurements are not recorded in extra columns but simply appended,
-leading to multiple occurrences of the sampling times \Robject{time}.
-
-Small to medium size dataset can be conveniently entered directly as \RR{} code
-as shown in the following listing
-
-<<data_format, echo=TRUE>>=
-example_data <- data.frame(
- name = rep("parent", 9),
- time = c(0, 1, 3, 7, 14, 28, 63, 91, 119),
- value = c(85.1, 57.9, 29.9, 14.6, 9.7, 6.6, 4, 3.9, 0.6)
-)
-@
-
-\subsection{Model definition}
-
-The next task is to define the model to be fitted to the data. In order to
-facilitate this task, a convenience function \Robject{mkinmod} is available.
-
-<<model_definition, echo=TRUE>>=
-SFO <- mkinmod(parent = list(type = "SFO"))
-SFORB <- mkinmod(parent = list(type = "SFORB"))
-SFO_SFO <- mkinmod(
- parent = list(type = "SFO", to = "m1", sink = TRUE),
- m1 = list(type = "SFO"))
-SFORB_SFO <- mkinmod(
- parent = list(type = "SFORB", to = "m1", sink = TRUE),
- m1 = list(type = "SFO"))
-@
-
-The model definitions given above define sets of linear first-order ordinary
-differential equations. In these cases, a coefficient matrix is also returned.
-
-Other models that include time on the right-hand side of the differential
-equation are the first-order multi-compartment (FOMC) model and the
-Hockey-Stick (HS) model. At present, only the FOMC model can only be used, and
-only for the parent compound.
-
-\subsection{Fitting the model}
-
-Then the model parameters should be fitted to the data. The function
-\Robject{mkinfit} internally creates a cost function using \Robject{modCost}
-from the \Rpackage{FME} package and the produces a fit using \Robject{modFit}
-from the same package. In cases of linear first-order differential
-equations, the solution used for calculating the cost function is based
-on the fundamental system of the coefficient matrix, as proposed by
-\citet{bates88}.
-
-<<model_fitting, echo=TRUE>>=
-# Do not show significance stars as they interfere with vignette generation
-options(show.signif.stars = FALSE)
-SFO.fit <- mkinfit(SFO, FOCUS_2006_C)
-summary(SFO.fit)
-SFORB.fit <- mkinfit(SFORB, FOCUS_2006_C)
-summary(SFORB.fit)
-SFO_SFO.fit <- mkinfit(SFO_SFO, FOCUS_2006_D, plot=TRUE)
-summary(SFO_SFO.fit, data=FALSE)
-SFORB_SFO.fit <- mkinfit(SFORB_SFO, FOCUS_2006_D, plot=TRUE)
-summary(SFORB_SFO.fit, data=FALSE)
-@
-
-\bibliographystyle{plainnat}
-\bibliography{references}
-
-\end{document}
-% vim: set foldmethod=syntax:
diff --git a/inst/doc/mkin.pdf b/inst/doc/mkin.pdf Binary files differdeleted file mode 100644 index f963d1e6..00000000 --- a/inst/doc/mkin.pdf +++ /dev/null diff --git a/inst/doc/references.bib b/inst/doc/references.bib deleted file mode 100644 index 24672e2e..00000000 --- a/inst/doc/references.bib +++ /dev/null @@ -1,62 +0,0 @@ -@Manual{pkg:kinfit,
- title = {kinfit: {R}outines for fitting simple kinetic models to chemical degradation data},
- author = {Johannes Ranke},
- year = {2010},
- url = {http://CRAN.R-project.org}
-}
-
-@Manual{pkg:mkin,
- title = {mkin: {R}outines for fitting kinetic models with one or more state variables to chemical degradation data},
- author = {Johannes Ranke},
- year = {2010},
- url = {http://CRAN.R-project.org}
-}
-
-@Article{soetaert10,
- title = {Inverse Modelling, Sensitivity and Monte Carlo Analysis in {R} Using Package {FME}},
- author = {Karline Soetaert and Thomas Petzoldt},
- journal = {Journal of Statistical Software},
- year = {2010},
- volume = {33},
- number = {3},
- pages = {1--28},
- url = {http://www.jstatsoft.org/v33/i03/}
-}
-
-@Manual{ rcore2010,
- title = {\textsf{R}: A Language and Environment for Statistical
- Computing},
- author = {{R Development Core Team}},
- organization = {R Foundation for Statistical Computing},
- address = {Vienna, Austria},
- year = 2010,
- note = {{ISBN} 3-900051-07-0},
- url = {http://www.R-project.org}
-}
-
-@Manual{ FOCUS2006,
- title = {Guidance Document on Estimating Persistence and
- Degradation Kinetics from Environmental Fate Studies on Pesticides in EU
- Registration. Report of the FOCUS Work Group on Degradation Kinetics},
- note = {EC Document Reference Sanco/10058/2005 version 2.0},
- author = {{FOCUS Work Group on Degradation Kinetics}},
- year = {2006},
- url = {http://focus.jrc.ec.europa.eu/dk}
-}
-
-@Inproceedings{ schaefer2007,
- title = {{KinGUI}: a new kinetic software tool for evaluations according to FOCUS degradation kinetics},
- author = {D. Sch\"{a}fer and M. Mikolasch and P. Rainbird and B. Harvey},
- booktitle = {Proceedings of the XIII Symposium Pesticide Chemistry},
- editor = {Del Re A. A. M. and Capri E. and Fragoulis G. and Trevisan M.},
- year = {2007},
- address = {Piacenza},
- pages = {916--923}
-}
-
-@Book{ bates88,
- title = {Nonlinear regression and its applications},
- author = {D. Bates and D. Watts},
- year = {1988},
- publisher = {Wiley-Interscience}
-}
diff --git a/inst/doc/run.bat b/inst/doc/run.bat deleted file mode 100644 index c28c6663..00000000 --- a/inst/doc/run.bat +++ /dev/null @@ -1,5 +0,0 @@ -R.exe -e "Sweave('mkin.Rnw', stylepath=FALSE)"
-pdflatex.exe mkin
-bibtex.exe mkin
-pdflatex.exe mkin
-pdflatex.exe mkin
|